Thiol-yne click chemistry on carbon nanotubes for mediated bioelectrocatalytic glucose oxidation

Monica Brachi; Fabien Giroud; Serge Cosnier; Alan Le Goff

doi:10.1039/d3ta05412h

Thiol-yne click chemistry on carbon nanotubes for mediated bioelectrocatalytic glucose oxidation

Monica Brachi
, Fabien Giroud
, Serge Cosnier
, Alan Le Goff

Centrum Elektroniki Organicznej i Nanohybrydowej (CONE)

Université Grenoble Alpes

Wyniki badań: Wkład do czasopisma › Artykuł › recenzja

5 Cytowania z bazy Scopus

Abstrakt

We report the modification of carbon nanotubes with both alkyne-modified diazonium salts and alkyne-modified pyrene followed by photo-irradiated thiol-yne click reaction with thiol-modified ferrocene and phenanthrenequinone derivatives. Photo-irradiation proves to provide the most efficient reaction yields for the thiol-yne reaction on surfaces, as demonstrated by electrochemistry and XPS. The as-functionalized carbon nanotubes achieve the mediated bioelectrocatalytic glucose oxidation by adsorbed flavin-dependent glucose dehydrogenases (FAD-GDH) at low overpotential and high current density of 4.80

Język oryginału	angielski
Strony (od–do)	26681-26686
Liczba stron	6
Czasopismo	Journal of Materials Chemistry A
Tom	11
Numer wydania	48
Identyfikatory DOI	https://doi.org/10.1039/d3ta05412h
Status publikacji	Opublikowano - 21 lis 2023

Obszary tematyczne ASJC Scopus

Chemia ogólna
Energia odnawialna, zrównoważony rozwój i środowisko
Materiałoznawstwo ogólne

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10.1039/d3ta05412h

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title = "Thiol-yne click chemistry on carbon nanotubes for mediated bioelectrocatalytic glucose oxidation",

abstract = "We report the modification of carbon nanotubes with both alkyne-modified diazonium salts and alkyne-modified pyrene followed by photo-irradiated thiol-yne click reaction with thiol-modified ferrocene and phenanthrenequinone derivatives. Photo-irradiation proves to provide the most efficient reaction yields for the thiol-yne reaction on surfaces, as demonstrated by electrochemistry and XPS. The as-functionalized carbon nanotubes achieve the mediated bioelectrocatalytic glucose oxidation by adsorbed flavin-dependent glucose dehydrogenases (FAD-GDH) at low overpotential and high current density of 4.80",

author = "Monica Brachi and Fabien Giroud and Serge Cosnier and \{Le Goff\}, Alan",

note = "Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry.",

year = "2023",

month = nov,

day = "21",

doi = "10.1039/d3ta05412h",

language = "English",

volume = "11",

pages = "26681--26686",

journal = "Journal of Materials Chemistry A",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Thiol-yne click chemistry on carbon nanotubes for mediated bioelectrocatalytic glucose oxidation

AU - Brachi, Monica

AU - Giroud, Fabien

AU - Cosnier, Serge

AU - Le Goff, Alan

PY - 2023/11/21

Y1 - 2023/11/21

N2 - We report the modification of carbon nanotubes with both alkyne-modified diazonium salts and alkyne-modified pyrene followed by photo-irradiated thiol-yne click reaction with thiol-modified ferrocene and phenanthrenequinone derivatives. Photo-irradiation proves to provide the most efficient reaction yields for the thiol-yne reaction on surfaces, as demonstrated by electrochemistry and XPS. The as-functionalized carbon nanotubes achieve the mediated bioelectrocatalytic glucose oxidation by adsorbed flavin-dependent glucose dehydrogenases (FAD-GDH) at low overpotential and high current density of 4.80

AB - We report the modification of carbon nanotubes with both alkyne-modified diazonium salts and alkyne-modified pyrene followed by photo-irradiated thiol-yne click reaction with thiol-modified ferrocene and phenanthrenequinone derivatives. Photo-irradiation proves to provide the most efficient reaction yields for the thiol-yne reaction on surfaces, as demonstrated by electrochemistry and XPS. The as-functionalized carbon nanotubes achieve the mediated bioelectrocatalytic glucose oxidation by adsorbed flavin-dependent glucose dehydrogenases (FAD-GDH) at low overpotential and high current density of 4.80

UR - https://www.scopus.com/pages/publications/85178556695

U2 - 10.1039/d3ta05412h

DO - 10.1039/d3ta05412h

M3 - Article

AN - SCOPUS:85178556695

SN - 2050-7488

VL - 11

SP - 26681

EP - 26686

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 48

ER -

Thiol-yne click chemistry on carbon nanotubes for mediated bioelectrocatalytic glucose oxidation

Abstrakt

Obszary tematyczne ASJC Scopus

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