Synthesis of dialkyl peroxides in the presence of polymer-supported phase-transfer catalysts

Stefan Baj; Agnieszka Siewniak; Beata Socha

doi:10.1016/j.apcata.2006.04.033

Synthesis of dialkyl peroxides in the presence of polymer-supported phase-transfer catalysts

Stefan Baj
, Agnieszka Siewniak
, Beata Socha

Katedra Technologii Chemicznej Organicznej i Petrochemii (RCH/RCH5)

Silesian University of Technology

Wyniki badań: Wkład do czasopisma › Artykuł › recenzja

26 Cytowania z bazy Scopus

Abstrakt

The synthesis of dialkyl peroxides from alkyl hydroperoxides and alkyl bromides in the presence of polymer-supported phase-transfer catalysts has been investigated. It was revealed that polymer-bound quaternary ammonium and polyethylene glycol catalysts were more active than their soluble forms. High yields (60-92%) of the products were obtained. The catalyst could be recycled several times with no appreciable loss of activity.

Język oryginału	angielski
Strony (od–do)	85-90
Liczba stron	6
Czasopismo	Applied Catalysis A: General
Tom	309
Numer wydania	1
Identyfikatory DOI	https://doi.org/10.1016/j.apcata.2006.04.033
Status publikacji	Opublikowano - 17 lip 2006

Obszary tematyczne ASJC Scopus

Kataliza
Chemia i technologia procesów

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10.1016/j.apcata.2006.04.033

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abstract = "The synthesis of dialkyl peroxides from alkyl hydroperoxides and alkyl bromides in the presence of polymer-supported phase-transfer catalysts has been investigated. It was revealed that polymer-bound quaternary ammonium and polyethylene glycol catalysts were more active than their soluble forms. High yields (60-92\%) of the products were obtained. The catalyst could be recycled several times with no appreciable loss of activity.",

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AU - Siewniak, Agnieszka

AU - Socha, Beata

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Y1 - 2006/7/17

N2 - The synthesis of dialkyl peroxides from alkyl hydroperoxides and alkyl bromides in the presence of polymer-supported phase-transfer catalysts has been investigated. It was revealed that polymer-bound quaternary ammonium and polyethylene glycol catalysts were more active than their soluble forms. High yields (60-92%) of the products were obtained. The catalyst could be recycled several times with no appreciable loss of activity.

AB - The synthesis of dialkyl peroxides from alkyl hydroperoxides and alkyl bromides in the presence of polymer-supported phase-transfer catalysts has been investigated. It was revealed that polymer-bound quaternary ammonium and polyethylene glycol catalysts were more active than their soluble forms. High yields (60-92%) of the products were obtained. The catalyst could be recycled several times with no appreciable loss of activity.

KW - Dialkyl peroxides

KW - Hydroperoxides

KW - Polymer-supported phase-transfer catalysts

KW - Triphase catalysis

UR - https://www.scopus.com/pages/publications/33745269797

U2 - 10.1016/j.apcata.2006.04.033

DO - 10.1016/j.apcata.2006.04.033

M3 - Article

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ER -

Synthesis of dialkyl peroxides in the presence of polymer-supported phase-transfer catalysts

Abstrakt

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