Synthesis of conducting polymers doped with heteropolyanions of Dawson-type structure

Mieczyslaw Łapkowski; Gerard Bidan; Michel Fournier

doi:10.1016/0379-6779(91)91095-R

Synthesis of conducting polymers doped with heteropolyanions of Dawson-type structure

Mieczyslaw Łapkowski
, Gerard Bidan
, Michel Fournier

Katedra Fizykochemii i Technologii Polimerów (RCH/RCH4)

Silesian University of Technology
Département de Recherche Fondamentale
Sorbonne Université

Wyniki badań: Wkład do czasopisma › Artykuł › recenzja

24 Cytowania z bazy Scopus

Abstrakt

Immobilization of Dawson-type heteropolyanions (HPA) such as: P₂W₁₈O₆₂ ^6- in poly(3-methyl-thiophene), and polyaniline is performed by electropolymerization of 3-methyl-thiophene (3-MeTh) and aniline (An) in nonaqueous solutions in the presence of corresponding heteropolyacids and salts. It was found possible to obtain electroactive films of polyaniline and polythiophene from acetonitrile solutions of HPA due to formation of respective HPA-An and HPA-3-MeTh complexes. These electrodes were characterized by cyclic voltammetry which provides three one-electron reversible HPA redox systems. They are stable in acidic solutions for poly(3-methylthiophene) and in acidic and neutral solutions for polyaniline.

Język oryginału	angielski
Strony (od–do)	411-414
Liczba stron	4
Czasopismo	Synthetic Metals
Tom	41
Numer wydania	1-2
Identyfikatory DOI	https://doi.org/10.1016/0379-6779(91)91095-R
Status publikacji	Opublikowano - 30 kwi 1991

Obszary tematyczne ASJC Scopus

Materiały elektroniczne, optyczne i magnetyczne
Fizyka materii skondensowanej
Mechanika materiałowa
Inżynieria mechaniczna
Metale i stopy
Chemia materiałowa

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10.1016/0379-6779(91)91095-R

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Cytowanie

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title = "Synthesis of conducting polymers doped with heteropolyanions of Dawson-type structure",

abstract = "Immobilization of Dawson-type heteropolyanions (HPA) such as: P2W18O62 6- in poly(3-methyl-thiophene), and polyaniline is performed by electropolymerization of 3-methyl-thiophene (3-MeTh) and aniline (An) in nonaqueous solutions in the presence of corresponding heteropolyacids and salts. It was found possible to obtain electroactive films of polyaniline and polythiophene from acetonitrile solutions of HPA due to formation of respective HPA-An and HPA-3-MeTh complexes. These electrodes were characterized by cyclic voltammetry which provides three one-electron reversible HPA redox systems. They are stable in acidic solutions for poly(3-methylthiophene) and in acidic and neutral solutions for polyaniline.",

author = "Mieczyslaw {\L}apkowski and Gerard Bidan and Michel Fournier",

year = "1991",

month = apr,

day = "30",

doi = "10.1016/0379-6779(91)91095-R",

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pages = "411--414",

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TY - JOUR

T1 - Synthesis of conducting polymers doped with heteropolyanions of Dawson-type structure

AU - Łapkowski, Mieczyslaw

AU - Bidan, Gerard

AU - Fournier, Michel

PY - 1991/4/30

Y1 - 1991/4/30

N2 - Immobilization of Dawson-type heteropolyanions (HPA) such as: P2W18O62 6- in poly(3-methyl-thiophene), and polyaniline is performed by electropolymerization of 3-methyl-thiophene (3-MeTh) and aniline (An) in nonaqueous solutions in the presence of corresponding heteropolyacids and salts. It was found possible to obtain electroactive films of polyaniline and polythiophene from acetonitrile solutions of HPA due to formation of respective HPA-An and HPA-3-MeTh complexes. These electrodes were characterized by cyclic voltammetry which provides three one-electron reversible HPA redox systems. They are stable in acidic solutions for poly(3-methylthiophene) and in acidic and neutral solutions for polyaniline.

AB - Immobilization of Dawson-type heteropolyanions (HPA) such as: P2W18O62 6- in poly(3-methyl-thiophene), and polyaniline is performed by electropolymerization of 3-methyl-thiophene (3-MeTh) and aniline (An) in nonaqueous solutions in the presence of corresponding heteropolyacids and salts. It was found possible to obtain electroactive films of polyaniline and polythiophene from acetonitrile solutions of HPA due to formation of respective HPA-An and HPA-3-MeTh complexes. These electrodes were characterized by cyclic voltammetry which provides three one-electron reversible HPA redox systems. They are stable in acidic solutions for poly(3-methylthiophene) and in acidic and neutral solutions for polyaniline.

UR - https://www.scopus.com/pages/publications/0026141428

U2 - 10.1016/0379-6779(91)91095-R

DO - 10.1016/0379-6779(91)91095-R

M3 - Article

AN - SCOPUS:0026141428

SN - 0379-6779

VL - 41

SP - 411

EP - 414

JO - Synthetic Metals

JF - Synthetic Metals

IS - 1-2

ER -

Synthesis of conducting polymers doped with heteropolyanions of Dawson-type structure

Abstrakt

Obszary tematyczne ASJC Scopus

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