Synthesis by Stille cross-coupling procedure and electrochemical characterization of branched polymers based on substituted 1,3,5-triarylbenzenes

A series of various substituted 1,3,5-triarylbenzenes, 2,4,6-triaryl-1- phenoles, 1,3,5-triaryl-1-methoxybenzenes and 2,4,6-triaryl-1,3,5- trimethoxybenzenes were synthesized by a Stille cross-coupling procedure. Their structures were confirmed by ¹H NMR, ¹³C NMR, and elemental analysis. Containing thienyl, furyl and EDOT groups polymers obtained in the process of electropolymerization could be carefully considered as a building material in a wide range of organic-electronic devices. We compare properties of monomers and related polymers depending on aryls moieties and their influence of hydroxyl and methoxyl groups attached to the central benzene core.