Surface Structure and Corrosion Behavior of Mg                         68−x                         Zn                         28+x                         Ca                         4                         (x = 0.4) Bulk Metallic Glasses after Immersion in Ringer’s Solution

Katarzyna Cesarz-Andraczke; Ryszard Nowosielski

doi:10.1007/s11665-019-04001-6

Surface Structure and Corrosion Behavior of Mg _68−x Zn _28+x Ca ₄ (x = 0.4) Bulk Metallic Glasses after Immersion in Ringer’s Solution

Katarzyna Cesarz-Andraczke
, Ryszard Nowosielski

Katedra Materiałów Inżynierskich i Biomedycznych (RMT/RMT1)

Wyniki badań: Wkład do czasopisma › Artykuł › recenzja

5 Cytowania z bazy Scopus

Abstrakt

The main aim of the present study was to determine the impact of Zn on the surface structure and corrosion behavior of Mg-based metallic glasses after immersion in Ringer’s solution. The corrosion rate expressed by the volume of released hydrogen in the form of a function of immersion time in Ringer’s solution at 37 °C was presented. The surface structure and corrosion products, which were formed during the immersion tests, were examined by means of scanning electron microscopy and the following spectroscopic methods: x-ray photoelectron spectroscopy, x-ray diffractometry, secondary ion mass spectrometry and energy-dispersive x-ray spectroscopy. As a result of the investigations of the surface structure, oxides (MgO, CaO, ZnO), hydroxides (Mg(OH) ₂ , Ca(OH) ₂ ) and carbonates (CaCO ₃ ) were identified. The analysis of the research results allowed the determination of a probable course and corrosion mechanism of the above-mentioned metallic glasses during immersion in Ringer’s solution.

Język oryginału	angielski
Strony (od–do)	2365-2377
Liczba stron	13
Czasopismo	Journal of Materials Engineering and Performance
Tom	28
Numer wydania	4
Identyfikatory DOI	https://doi.org/10.1007/s11665-019-04001-6
Status publikacji	Opublikowano - 1 kwi 2019

Obszary tematyczne ASJC Scopus

Materiałoznawstwo ogólne
Mechanika materiałowa
Inżynieria mechaniczna

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10.1007/s11665-019-04001-6

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Cytowanie

Cesarz-Andraczke, K., & Nowosielski, R. (2019). Surface Structure and Corrosion Behavior of Mg _68−x Zn _28+x Ca ₄ (x = 0.4) Bulk Metallic Glasses after Immersion in Ringer’s Solution Journal of Materials Engineering and Performance, 28(4), 2365-2377. https://doi.org/10.1007/s11665-019-04001-6

Cesarz-Andraczke, Katarzyna ; Nowosielski, Ryszard. / Surface Structure and Corrosion Behavior of Mg _68−x Zn _28+x Ca ₄ (x = 0.4) Bulk Metallic Glasses after Immersion in Ringer’s Solution W: Journal of Materials Engineering and Performance. 2019 ; Tom 28, Nr 4. str. 2365-2377.

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title = " Surface Structure and Corrosion Behavior of Mg 68−x Zn 28+x Ca 4 (x = 0.4) Bulk Metallic Glasses after Immersion in Ringer{\textquoteright}s Solution ",

abstract = " The main aim of the present study was to determine the impact of Zn on the surface structure and corrosion behavior of Mg-based metallic glasses after immersion in Ringer{\textquoteright}s solution. The corrosion rate expressed by the volume of released hydrogen in the form of a function of immersion time in Ringer{\textquoteright}s solution at 37 °C was presented. The surface structure and corrosion products, which were formed during the immersion tests, were examined by means of scanning electron microscopy and the following spectroscopic methods: x-ray photoelectron spectroscopy, x-ray diffractometry, secondary ion mass spectrometry and energy-dispersive x-ray spectroscopy. As a result of the investigations of the surface structure, oxides (MgO, CaO, ZnO), hydroxides (Mg(OH) 2 , Ca(OH) 2 ) and carbonates (CaCO 3 ) were identified. The analysis of the research results allowed the determination of a probable course and corrosion mechanism of the above-mentioned metallic glasses during immersion in Ringer{\textquoteright}s solution.",

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Cesarz-Andraczke, K & Nowosielski, R 2019, ' Surface Structure and Corrosion Behavior of Mg _68−x Zn _28+x Ca ₄ (x = 0.4) Bulk Metallic Glasses after Immersion in Ringer’s Solution ', Journal of Materials Engineering and Performance, tom 28, nr 4, str. 2365-2377. https://doi.org/10.1007/s11665-019-04001-6

Surface Structure and Corrosion Behavior of Mg _68−x Zn _28+x Ca ₄ (x = 0.4) Bulk Metallic Glasses after Immersion in Ringer’s Solution . / Cesarz-Andraczke, Katarzyna; Nowosielski, Ryszard.
W: Journal of Materials Engineering and Performance, Tom 28, Nr 4, 01.04.2019, str. 2365-2377.

Wyniki badań: Wkład do czasopisma › Artykuł › recenzja

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AU - Cesarz-Andraczke, Katarzyna

AU - Nowosielski, Ryszard

PY - 2019/4/1

Y1 - 2019/4/1

N2 - The main aim of the present study was to determine the impact of Zn on the surface structure and corrosion behavior of Mg-based metallic glasses after immersion in Ringer’s solution. The corrosion rate expressed by the volume of released hydrogen in the form of a function of immersion time in Ringer’s solution at 37 °C was presented. The surface structure and corrosion products, which were formed during the immersion tests, were examined by means of scanning electron microscopy and the following spectroscopic methods: x-ray photoelectron spectroscopy, x-ray diffractometry, secondary ion mass spectrometry and energy-dispersive x-ray spectroscopy. As a result of the investigations of the surface structure, oxides (MgO, CaO, ZnO), hydroxides (Mg(OH) 2 , Ca(OH) 2 ) and carbonates (CaCO 3 ) were identified. The analysis of the research results allowed the determination of a probable course and corrosion mechanism of the above-mentioned metallic glasses during immersion in Ringer’s solution.

AB - The main aim of the present study was to determine the impact of Zn on the surface structure and corrosion behavior of Mg-based metallic glasses after immersion in Ringer’s solution. The corrosion rate expressed by the volume of released hydrogen in the form of a function of immersion time in Ringer’s solution at 37 °C was presented. The surface structure and corrosion products, which were formed during the immersion tests, were examined by means of scanning electron microscopy and the following spectroscopic methods: x-ray photoelectron spectroscopy, x-ray diffractometry, secondary ion mass spectrometry and energy-dispersive x-ray spectroscopy. As a result of the investigations of the surface structure, oxides (MgO, CaO, ZnO), hydroxides (Mg(OH) 2 , Ca(OH) 2 ) and carbonates (CaCO 3 ) were identified. The analysis of the research results allowed the determination of a probable course and corrosion mechanism of the above-mentioned metallic glasses during immersion in Ringer’s solution.

KW - amorphous magnesium alloys

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KW - corrosion products

KW - resorbable metallic alloys

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Cesarz-Andraczke K, Nowosielski R. Surface Structure and Corrosion Behavior of Mg _68−x Zn _28+x Ca ₄ (x = 0.4) Bulk Metallic Glasses after Immersion in Ringer’s Solution Journal of Materials Engineering and Performance. 2019 kwi 1;28(4):2365-2377. doi: 10.1007/s11665-019-04001-6

Surface Structure and Corrosion Behavior of Mg 68−x Zn 28+x Ca 4 (x = 0.4) Bulk Metallic Glasses after Immersion in Ringer’s Solution