Preparation of poly(isothianaphthene) from 2,5-bis(trialkylsilyl)isothianaphthenes

M. Łapkowski; R. Kiebooms; A. Proń; O. Chauvet; J. Gelan; D. Vanderzande; S. Lefrant

doi:10.1016/s0379-6779(97)80808-9

Preparation of poly(isothianaphthene) from 2,5-bis(trialkylsilyl)isothianaphthenes

M. Łapkowski
, R. Kiebooms
, A. Proń
, O. Chauvet
, J. Gelan
, D. Vanderzande
, S. Lefrant

Katedra Fizykochemii i Technologii Polimerów (RCH/RCH4)

University of Bielsko-Biala
Hasselt University
AGH University of Krakow
Warsaw University of Technology
Nantes Université

Wyniki badań: Wkład do czasopisma › Artykuł › recenzja

2 Cytowania z bazy Scopus

Abstrakt

It is demonstrated that the anodic oxidation of 2,5-bis(tert-butyldimethylsilyl) isothianaphthene in Bu₄NBF₄/nitrobenzene electrolyte results in the formation of poly(isothianaphthene) film with an average polymerization degree of 20. Disilylated isothianaphthene dimer and trimer do not polymerize in this electrolyte giving upon anodic oxidation stable radical cations and dications.

Język oryginału	angielski
Strony (od–do)	413-414
Liczba stron	2
Czasopismo	Synthetic Metals
Tom	84
Numer wydania	1-3
Identyfikatory DOI	https://doi.org/10.1016/s0379-6779(97)80808-9
Status publikacji	Opublikowano - sty 1997

Obszary tematyczne ASJC Scopus

Materiały elektroniczne, optyczne i magnetyczne
Fizyka materii skondensowanej
Mechanika materiałowa
Inżynieria mechaniczna
Metale i stopy
Chemia materiałowa

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10.1016/s0379-6779(97)80808-9

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Cytowanie

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title = "Preparation of poly(isothianaphthene) from 2,5-bis(trialkylsilyl)isothianaphthenes",

abstract = "It is demonstrated that the anodic oxidation of 2,5-bis(tert-butyldimethylsilyl) isothianaphthene in Bu4NBF4/nitrobenzene electrolyte results in the formation of poly(isothianaphthene) film with an average polymerization degree of 20. Disilylated isothianaphthene dimer and trimer do not polymerize in this electrolyte giving upon anodic oxidation stable radical cations and dications.",

keywords = "Electrochemistry, Poly(isothianaphthene), Raman spectroelectrochemistry, Spectroelectrochemistry",

author = "M. {\L}apkowski and R. Kiebooms and A. Pro{\'n} and O. Chauvet and J. Gelan and D. Vanderzande and S. Lefrant",

year = "1997",

month = jan,

doi = "10.1016/s0379-6779(97)80808-9",

language = "English",

volume = "84",

pages = "413--414",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier B.V.",

number = "1-3",

}

TY - JOUR

T1 - Preparation of poly(isothianaphthene) from 2,5-bis(trialkylsilyl)isothianaphthenes

AU - Łapkowski, M.

AU - Kiebooms, R.

AU - Proń, A.

AU - Chauvet, O.

AU - Gelan, J.

AU - Vanderzande, D.

AU - Lefrant, S.

PY - 1997/1

Y1 - 1997/1

N2 - It is demonstrated that the anodic oxidation of 2,5-bis(tert-butyldimethylsilyl) isothianaphthene in Bu4NBF4/nitrobenzene electrolyte results in the formation of poly(isothianaphthene) film with an average polymerization degree of 20. Disilylated isothianaphthene dimer and trimer do not polymerize in this electrolyte giving upon anodic oxidation stable radical cations and dications.

AB - It is demonstrated that the anodic oxidation of 2,5-bis(tert-butyldimethylsilyl) isothianaphthene in Bu4NBF4/nitrobenzene electrolyte results in the formation of poly(isothianaphthene) film with an average polymerization degree of 20. Disilylated isothianaphthene dimer and trimer do not polymerize in this electrolyte giving upon anodic oxidation stable radical cations and dications.

KW - Electrochemistry

KW - Poly(isothianaphthene)

KW - Raman spectroelectrochemistry

KW - Spectroelectrochemistry

UR - https://www.scopus.com/pages/publications/0030714793

U2 - 10.1016/s0379-6779(97)80808-9

DO - 10.1016/s0379-6779(97)80808-9

M3 - Article

AN - SCOPUS:0030714793

SN - 0379-6779

VL - 84

SP - 413

EP - 414

JO - Synthetic Metals

JF - Synthetic Metals

IS - 1-3

ER -

Preparation of poly(isothianaphthene) from 2,5-bis(trialkylsilyl)isothianaphthenes

Abstrakt

Obszary tematyczne ASJC Scopus

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