Oxidation of long-chain α-olefins using environmentally-friendly oxidants

Kamil Peckh; Dawid Lisicki; Gabriela Talik; Beata Orlińska

doi:10.3390/ma13204545

Oxidation of long-chain α-olefins using environmentally-friendly oxidants

Katedra Technologii Chemicznej Organicznej i Petrochemii (RCH/RCH5)

Silesian University of Technology

Wyniki badań: Wkład do czasopisma › Artykuł › recenzja

9 Cytowania z bazy Scopus

Abstrakt

Studies on the oxidation of α-olefins via the two-stage method are presented. The new method consisted of oxidizing C30+ α-olefins with hydrogen peroxide (2 equiv.) and subsequent oxidation with oxygen. Products with high acid numbers (29–82 mgKOH/g) and saponification numbers (64–140 mgKOH/g) were obtained and compared with products obtained using only hydrogen peroxide or oxygen. It was demonstrated that H₂O₂ can be partially replaced by oxygen in the oxidative cleavage reaction of α-olefins. N-hydroxyphthalimide in combination with Co(acac)₂ demonstrated high activity in the oxidation stage using oxygen.

Język oryginału	angielski
Numer artykułu	4545
Strony (od–do)	1-14
Liczba stron	14
Czasopismo	Materials
Tom	13
Numer wydania	20
Identyfikatory DOI	https://doi.org/10.3390/ma13204545
Status publikacji	Opublikowano - 2 paź 2020

Obszary tematyczne ASJC Scopus

Materiałoznawstwo ogólne
Fizyka materii skondensowanej

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title = "Oxidation of long-chain α-olefins using environmentally-friendly oxidants",

abstract = "Studies on the oxidation of α-olefins via the two-stage method are presented. The new method consisted of oxidizing C30+ α-olefins with hydrogen peroxide (2 equiv.) and subsequent oxidation with oxygen. Products with high acid numbers (29–82 mgKOH/g) and saponification numbers (64–140 mgKOH/g) were obtained and compared with products obtained using only hydrogen peroxide or oxygen. It was demonstrated that H2O2 can be partially replaced by oxygen in the oxidative cleavage reaction of α-olefins. N-hydroxyphthalimide in combination with Co(acac)2 demonstrated high activity in the oxidation stage using oxygen.",

keywords = "N-hydroxyphthalimide, Oxidation, Oxidative cleavage, α-olefins",

author = "Kamil Peckh and Dawid Lisicki and Gabriela Talik and Beata Orli{\'n}ska",

note = "Publisher Copyright: {\textcopyright} 2020 by the authors.",

year = "2020",

month = oct,

day = "2",

doi = "10.3390/ma13204545",

language = "English",

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journal = "Materials",

issn = "1996-1944",

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TY - JOUR

T1 - Oxidation of long-chain α-olefins using environmentally-friendly oxidants

AU - Peckh, Kamil

AU - Lisicki, Dawid

AU - Talik, Gabriela

AU - Orlińska, Beata

PY - 2020/10/2

Y1 - 2020/10/2

N2 - Studies on the oxidation of α-olefins via the two-stage method are presented. The new method consisted of oxidizing C30+ α-olefins with hydrogen peroxide (2 equiv.) and subsequent oxidation with oxygen. Products with high acid numbers (29–82 mgKOH/g) and saponification numbers (64–140 mgKOH/g) were obtained and compared with products obtained using only hydrogen peroxide or oxygen. It was demonstrated that H2O2 can be partially replaced by oxygen in the oxidative cleavage reaction of α-olefins. N-hydroxyphthalimide in combination with Co(acac)2 demonstrated high activity in the oxidation stage using oxygen.

AB - Studies on the oxidation of α-olefins via the two-stage method are presented. The new method consisted of oxidizing C30+ α-olefins with hydrogen peroxide (2 equiv.) and subsequent oxidation with oxygen. Products with high acid numbers (29–82 mgKOH/g) and saponification numbers (64–140 mgKOH/g) were obtained and compared with products obtained using only hydrogen peroxide or oxygen. It was demonstrated that H2O2 can be partially replaced by oxygen in the oxidative cleavage reaction of α-olefins. N-hydroxyphthalimide in combination with Co(acac)2 demonstrated high activity in the oxidation stage using oxygen.

KW - N-hydroxyphthalimide

KW - Oxidation

KW - Oxidative cleavage

KW - α-olefins

UR - https://www.scopus.com/pages/publications/85095713067

U2 - 10.3390/ma13204545

DO - 10.3390/ma13204545

M3 - Article

AN - SCOPUS:85095713067

SN - 1996-1944

VL - 13

SP - 1

EP - 14

JO - Materials

JF - Materials

IS - 20

M1 - 4545

ER -

Oxidation of long-chain α-olefins using environmentally-friendly oxidants

Abstrakt

Obszary tematyczne ASJC Scopus

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