Oxidation of cycloalkanes catalysed by N-hydroxyimides in supercritical carbon dioxide

Dawid Lisicki; Beata Orlińska

doi:10.1007/s11696-019-00937-0

Oxidation of cycloalkanes catalysed by N-hydroxyimides in supercritical carbon dioxide

Katedra Technologii Chemicznej Organicznej i Petrochemii (RCH/RCH5)

Wyniki badań: Wkład do czasopisma › Artykuł › recenzja

11 Cytowania z bazy Scopus

Abstrakt

This paper reports cyclopentane, cyclohexane and cyclooctane oxidation in the presence of N-hydroxyphthalimide or 4-dodecyloxycarbonyl-N-hydroxyphthalimide in combination with Co(II) and Fe(II) salts using O₂/CO₂ mixture (0.5 MPa O₂, 9.5 MPa CO₂). The studies demonstrated that the application of scCO₂ in cyclohexane and cyclooctane oxidation processes results in higher conversion and yield of respective ketone and alcohol in comparison to processes performed using air under pressure (0.7 MPa).

Język oryginału	angielski
Strony (od–do)	711-716
Liczba stron	6
Czasopismo	Chemical Papers
Tom	74
Numer wydania	2
Identyfikatory DOI	https://doi.org/10.1007/s11696-019-00937-0
Status publikacji	Opublikowano - 1 lut 2020

Obszary tematyczne ASJC Scopus

Chemia ogólna
Biochemia
Ogólna inżynieria chemiczna
Inżynieria przemysłowa i produkcyjna
Chemia materiałowa

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10.1007/s11696-019-00937-0

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Cytowanie

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title = "Oxidation of cycloalkanes catalysed by N-hydroxyimides in supercritical carbon dioxide",

abstract = "This paper reports cyclopentane, cyclohexane and cyclooctane oxidation in the presence of N-hydroxyphthalimide or 4-dodecyloxycarbonyl-N-hydroxyphthalimide in combination with Co(II) and Fe(II) salts using O2/CO2 mixture (0.5 MPa O2, 9.5 MPa CO2). The studies demonstrated that the application of scCO2 in cyclohexane and cyclooctane oxidation processes results in higher conversion and yield of respective ketone and alcohol in comparison to processes performed using air under pressure (0.7 MPa).",

keywords = "Carbon dioxide, Cyclohexane, Cyclooctane, Cyclopentane, N-Hydroxyphthalimide, Oxidation",

author = "Dawid Lisicki and Beata Orli{\'n}ska",

note = "Publisher Copyright: {\textcopyright} 2019, The Author(s).",

year = "2020",

month = feb,

day = "1",

doi = "10.1007/s11696-019-00937-0",

language = "English",

volume = "74",

pages = "711--716",

journal = "Chemical Papers",

issn = "0366-6352",

publisher = "Springer International Publishing AG",

number = "2",

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TY - JOUR

T1 - Oxidation of cycloalkanes catalysed by N-hydroxyimides in supercritical carbon dioxide

AU - Lisicki, Dawid

AU - Orlińska, Beata

PY - 2020/2/1

Y1 - 2020/2/1

N2 - This paper reports cyclopentane, cyclohexane and cyclooctane oxidation in the presence of N-hydroxyphthalimide or 4-dodecyloxycarbonyl-N-hydroxyphthalimide in combination with Co(II) and Fe(II) salts using O2/CO2 mixture (0.5 MPa O2, 9.5 MPa CO2). The studies demonstrated that the application of scCO2 in cyclohexane and cyclooctane oxidation processes results in higher conversion and yield of respective ketone and alcohol in comparison to processes performed using air under pressure (0.7 MPa).

AB - This paper reports cyclopentane, cyclohexane and cyclooctane oxidation in the presence of N-hydroxyphthalimide or 4-dodecyloxycarbonyl-N-hydroxyphthalimide in combination with Co(II) and Fe(II) salts using O2/CO2 mixture (0.5 MPa O2, 9.5 MPa CO2). The studies demonstrated that the application of scCO2 in cyclohexane and cyclooctane oxidation processes results in higher conversion and yield of respective ketone and alcohol in comparison to processes performed using air under pressure (0.7 MPa).

KW - Carbon dioxide

KW - Cyclohexane

KW - Cyclooctane

KW - Cyclopentane

KW - N-Hydroxyphthalimide

KW - Oxidation

UR - https://www.scopus.com/pages/publications/85074012591

U2 - 10.1007/s11696-019-00937-0

DO - 10.1007/s11696-019-00937-0

M3 - Article

AN - SCOPUS:85074012591

SN - 0366-6352

VL - 74

SP - 711

EP - 716

JO - Chemical Papers

JF - Chemical Papers

IS - 2

ER -

Oxidation of cycloalkanes catalysed by N-hydroxyimides in supercritical carbon dioxide

Abstrakt

Obszary tematyczne ASJC Scopus

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