Liquid-phase oxidation of 1-isopropyl- and 1-ethyl-4-methoxybenzenes with oxygen to hydroperoxides

Jan Zawadiak; Zbigniew Stec; Bartlomiej Jakubowski; Beata Orlińska

doi:10.1002/kin.10108

Liquid-phase oxidation of 1-isopropyl- and 1-ethyl-4-methoxybenzenes with oxygen to hydroperoxides

Jan Zawadiak
, Zbigniew Stec
, Bartlomiej Jakubowski
, Beata Orlińska

Katedra Technologii Chemicznej Organicznej i Petrochemii (RCH/RCH5)

Silesian University of Technology

Wyniki badań: Wkład do czasopisma › Artykuł › recenzja

7 Cytowania z bazy Scopus

Abstrakt

A study was carried out on the kinetics of free-radical chain oxidation of 1-isopropyl-4-methoxybenzene (1a) and 1-ethyl-4-methoxybenzene (1b) with oxygen in the liquid phase to yield 1-methyl-1-(4-methoxyphenyl)ethyl hydroperoxide (2a) and 1-(4-methoxyphenyl)ethyl hydroperoxide (2b). The oxidizability of 1a and 1b was studied over the temperature range 50-100°C. Long-term oxidations of 1a and 1b to the corresponding hydroperoxides were carried out and the properties and thermal stability of 2a were established.

Język oryginału	angielski
Strony (od–do)	89-94
Liczba stron	6
Czasopismo	International Journal of Chemical Kinetics
Tom	35
Numer wydania	3
Identyfikatory DOI	https://doi.org/10.1002/kin.10108
Status publikacji	Opublikowano - mar 2003

Obszary tematyczne ASJC Scopus

Biochemia
Chemia fizyczna i teoretyczna
Chemia organiczna
Chemia nieorganiczna

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10.1002/kin.10108

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title = "Liquid-phase oxidation of 1-isopropyl- and 1-ethyl-4-methoxybenzenes with oxygen to hydroperoxides",

abstract = "A study was carried out on the kinetics of free-radical chain oxidation of 1-isopropyl-4-methoxybenzene (1a) and 1-ethyl-4-methoxybenzene (1b) with oxygen in the liquid phase to yield 1-methyl-1-(4-methoxyphenyl)ethyl hydroperoxide (2a) and 1-(4-methoxyphenyl)ethyl hydroperoxide (2b). The oxidizability of 1a and 1b was studied over the temperature range 50-100°C. Long-term oxidations of 1a and 1b to the corresponding hydroperoxides were carried out and the properties and thermal stability of 2a were established.",

author = "Jan Zawadiak and Zbigniew Stec and Bartlomiej Jakubowski and Beata Orli{\'n}ska",

year = "2003",

month = mar,

doi = "10.1002/kin.10108",

language = "English",

volume = "35",

pages = "89--94",

journal = "International Journal of Chemical Kinetics",

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TY - JOUR

T1 - Liquid-phase oxidation of 1-isopropyl- and 1-ethyl-4-methoxybenzenes with oxygen to hydroperoxides

AU - Zawadiak, Jan

AU - Stec, Zbigniew

AU - Jakubowski, Bartlomiej

AU - Orlińska, Beata

PY - 2003/3

Y1 - 2003/3

N2 - A study was carried out on the kinetics of free-radical chain oxidation of 1-isopropyl-4-methoxybenzene (1a) and 1-ethyl-4-methoxybenzene (1b) with oxygen in the liquid phase to yield 1-methyl-1-(4-methoxyphenyl)ethyl hydroperoxide (2a) and 1-(4-methoxyphenyl)ethyl hydroperoxide (2b). The oxidizability of 1a and 1b was studied over the temperature range 50-100°C. Long-term oxidations of 1a and 1b to the corresponding hydroperoxides were carried out and the properties and thermal stability of 2a were established.

AB - A study was carried out on the kinetics of free-radical chain oxidation of 1-isopropyl-4-methoxybenzene (1a) and 1-ethyl-4-methoxybenzene (1b) with oxygen in the liquid phase to yield 1-methyl-1-(4-methoxyphenyl)ethyl hydroperoxide (2a) and 1-(4-methoxyphenyl)ethyl hydroperoxide (2b). The oxidizability of 1a and 1b was studied over the temperature range 50-100°C. Long-term oxidations of 1a and 1b to the corresponding hydroperoxides were carried out and the properties and thermal stability of 2a were established.

UR - https://www.scopus.com/pages/publications/0037374421

U2 - 10.1002/kin.10108

DO - 10.1002/kin.10108

M3 - Article

AN - SCOPUS:0037374421

SN - 0538-8066

VL - 35

SP - 89

EP - 94

JO - International Journal of Chemical Kinetics

JF - International Journal of Chemical Kinetics

IS - 3

ER -

Liquid-phase oxidation of 1-isopropyl- and 1-ethyl-4-methoxybenzenes with oxygen to hydroperoxides

Abstrakt

Obszary tematyczne ASJC Scopus

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