Electrochemical and spectroelectrochemical evidence of dimerization and oligomerization during the polymerization of terthiophenes

M. Jadamiec; M. Lapkowski; M. Matlengiewicz; A. Brembilla; B. Henry; L. Rodehüser

doi:10.1016/j.electacta.2007.04.011

Electrochemical and spectroelectrochemical evidence of dimerization and oligomerization during the polymerization of terthiophenes

M. Jadamiec
, M. Lapkowski
, M. Matlengiewicz
, A. Brembilla
, B. Henry
, L. Rodehüser

Katedra Fizykochemii i Technologii Polimerów (RCH/RCH4)

Polish Academy of Sciences
University of Silesia in Katowice
UMR 7565 Université Nancy 1

Wyniki badań: Wkład do czasopisma › Artykuł › recenzja

21 Cytowania z bazy Scopus

Abstrakt

Electrochemical oxidation of terthiophenes leads to polymers forming electroactive layers on the electrode surface. Application of spectroelectrochemical methods and special measurement procedure make it possible to show that intermediate products are formed during polymerization. Detailed spectroscopic analyses reveal the presence of terthiophene dimer, trimer and tetramer which allow to propose a mechanism of polymerization process.

Język oryginału	angielski
Strony (od–do)	6146-6154
Liczba stron	9
Czasopismo	Electrochimica Acta
Tom	52
Numer wydania	20
Identyfikatory DOI	https://doi.org/10.1016/j.electacta.2007.04.011
Status publikacji	Opublikowano - 10 cze 2007

Obszary tematyczne ASJC Scopus

Ogólna inżynieria chemiczna
Elektrochemia

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10.1016/j.electacta.2007.04.011

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Cytowanie

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abstract = "Electrochemical oxidation of terthiophenes leads to polymers forming electroactive layers on the electrode surface. Application of spectroelectrochemical methods and special measurement procedure make it possible to show that intermediate products are formed during polymerization. Detailed spectroscopic analyses reveal the presence of terthiophene dimer, trimer and tetramer which allow to propose a mechanism of polymerization process.",

keywords = "Electrochemistry, Polymerization mechanism, Polythiophene, Spectroelectrochemistry, Terthiophene",

author = "M. Jadamiec and M. Lapkowski and M. Matlengiewicz and A. Brembilla and B. Henry and L. Rodeh{\"u}ser",

year = "2007",

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doi = "10.1016/j.electacta.2007.04.011",

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TY - JOUR

T1 - Electrochemical and spectroelectrochemical evidence of dimerization and oligomerization during the polymerization of terthiophenes

AU - Jadamiec, M.

AU - Lapkowski, M.

AU - Matlengiewicz, M.

AU - Brembilla, A.

AU - Henry, B.

AU - Rodehüser, L.

PY - 2007/6/10

Y1 - 2007/6/10

N2 - Electrochemical oxidation of terthiophenes leads to polymers forming electroactive layers on the electrode surface. Application of spectroelectrochemical methods and special measurement procedure make it possible to show that intermediate products are formed during polymerization. Detailed spectroscopic analyses reveal the presence of terthiophene dimer, trimer and tetramer which allow to propose a mechanism of polymerization process.

AB - Electrochemical oxidation of terthiophenes leads to polymers forming electroactive layers on the electrode surface. Application of spectroelectrochemical methods and special measurement procedure make it possible to show that intermediate products are formed during polymerization. Detailed spectroscopic analyses reveal the presence of terthiophene dimer, trimer and tetramer which allow to propose a mechanism of polymerization process.

KW - Electrochemistry

KW - Polymerization mechanism

KW - Polythiophene

KW - Spectroelectrochemistry

KW - Terthiophene

UR - https://www.scopus.com/pages/publications/34248361842

U2 - 10.1016/j.electacta.2007.04.011

DO - 10.1016/j.electacta.2007.04.011

M3 - Article

AN - SCOPUS:34248361842

SN - 0013-4686

VL - 52

SP - 6146

EP - 6154

JO - Electrochimica Acta

JF - Electrochimica Acta

IS - 20

ER -

Electrochemical and spectroelectrochemical evidence of dimerization and oligomerization during the polymerization of terthiophenes

Abstrakt

Obszary tematyczne ASJC Scopus

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