Copper (II) chloride / tetrabutylammonium bromide catalyzed oxidation of 2,6-diisopropylnaphthalene and 4,4′-diisopropylbiphenyl

Beata J. Orlińska; Jan M. Zawadiak

doi:10.2478/s11532-009-0134-8

Copper (II) chloride / tetrabutylammonium bromide catalyzed oxidation of 2,6-diisopropylnaphthalene and 4,4′-diisopropylbiphenyl

Beata J. Orlińska
, Jan M. Zawadiak

Katedra Technologii Chemicznej Organicznej i Petrochemii (RCH/RCH5)

Wyniki badań: Wkład do czasopisma › Artykuł › recenzja

3 Cytowania z bazy Scopus

Abstrakt

The oxidation processes of 2,6-diisopropylnaphthalene and 4,4′-diisopropylbiphenyl with oxygen in the presence of a catalyst, composed of copper(II) chloride and tetrabutylammonium bromide, were investigated. It was found that, in essence, only one isopropyl group undergoes oxidation, and obtained mixtures contained mainly peroxide, alcohol, ketone and only small amounts of hydroperoxide.

Język oryginału	angielski
Strony (od–do)	285-290
Liczba stron	6
Czasopismo	Central European Journal of Chemistry
Tom	8
Numer wydania	2
Identyfikatory DOI	https://doi.org/10.2478/s11532-009-0134-8
Status publikacji	Opublikowano - kwi 2010

Obszary tematyczne ASJC Scopus

Chemia ogólna
Chemia materiałowa

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10.2478/s11532-009-0134-8

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Cytowanie

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title = "Copper (II) chloride / tetrabutylammonium bromide catalyzed oxidation of 2,6-diisopropylnaphthalene and 4,4′-diisopropylbiphenyl",

abstract = "The oxidation processes of 2,6-diisopropylnaphthalene and 4,4′-diisopropylbiphenyl with oxygen in the presence of a catalyst, composed of copper(II) chloride and tetrabutylammonium bromide, were investigated. It was found that, in essence, only one isopropyl group undergoes oxidation, and obtained mixtures contained mainly peroxide, alcohol, ketone and only small amounts of hydroperoxide.",

keywords = "2,6-Diisopropylnaphthalene, 4,4′-Diisopropylbiphenyl, Catalytic oxidation, Peroxides",

author = "Orli{\'n}ska, \{Beata J.\} and Zawadiak, \{Jan M.\}",

year = "2010",

month = apr,

doi = "10.2478/s11532-009-0134-8",

language = "English",

volume = "8",

pages = "285--290",

journal = "Central European Journal of Chemistry",

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TY - JOUR

T1 - Copper (II) chloride / tetrabutylammonium bromide catalyzed oxidation of 2,6-diisopropylnaphthalene and 4,4′-diisopropylbiphenyl

AU - Orlińska, Beata J.

AU - Zawadiak, Jan M.

PY - 2010/4

Y1 - 2010/4

N2 - The oxidation processes of 2,6-diisopropylnaphthalene and 4,4′-diisopropylbiphenyl with oxygen in the presence of a catalyst, composed of copper(II) chloride and tetrabutylammonium bromide, were investigated. It was found that, in essence, only one isopropyl group undergoes oxidation, and obtained mixtures contained mainly peroxide, alcohol, ketone and only small amounts of hydroperoxide.

AB - The oxidation processes of 2,6-diisopropylnaphthalene and 4,4′-diisopropylbiphenyl with oxygen in the presence of a catalyst, composed of copper(II) chloride and tetrabutylammonium bromide, were investigated. It was found that, in essence, only one isopropyl group undergoes oxidation, and obtained mixtures contained mainly peroxide, alcohol, ketone and only small amounts of hydroperoxide.

KW - 2,6-Diisopropylnaphthalene

KW - 4,4′-Diisopropylbiphenyl

KW - Catalytic oxidation

KW - Peroxides

UR - https://www.scopus.com/pages/publications/77951862184

U2 - 10.2478/s11532-009-0134-8

DO - 10.2478/s11532-009-0134-8

M3 - Article

AN - SCOPUS:77951862184

SN - 1895-1066

VL - 8

SP - 285

EP - 290

JO - Central European Journal of Chemistry

JF - Central European Journal of Chemistry

IS - 2

ER -

Copper (II) chloride / tetrabutylammonium bromide catalyzed oxidation of 2,6-diisopropylnaphthalene and 4,4′-diisopropylbiphenyl

Abstrakt

Obszary tematyczne ASJC Scopus

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