A novel approach to peatlands as archives of total cumulative spatial pollution loads from atmospheric deposition of airborne elements complementary to EMEP data: priority pollutants (Pb, Cd, Hg)

A novel approach to using peatlands for assessment of cumulative contributions from long-range transport of pollutants (LRTP) – airborne trace elements – to spatial pollution was exemplified in evaluating retrospective atmospheric deposition of priority pollutants (Pb, Cd, Hg) in peat bogs in Norway in areas minor affected by local sources of pollution and in NW Poland located on the way of possible LRTP from Poland to Norway. Peat from the corresponding ¹⁴C-dated layers of five ombrotrophic bogs in each country, was analysed for trace element contents. Pollutant concentrations/load distribution along the peat profiles related to bulk density has given a clear evidence of uneven density-dependent temporal vertical migration of all studied elements that distorts the chronology of their deposition. Much higher loads of Pb, Cd and Hg in southern Norwegian bogs than in bogs located in NW Poland proved transboundary transport from neighbouring highly industrialized European countries to be much more significant contributor to high deposition of the priority pollutants in this area and rather excludes LRTP from Poland as a major source of total land pollution in southernmost Norway. The study showed excellent applicability of peat bogs for the exact assessment of retrospective cumulative pollutant loads from LRTP, but not for the identification of deposition chronology. Combining the use of ombrotrophic peat bogs as tools for retrospective monitoring of cumulative land pollution with airborne elements with current LRTP data within the Cooperative Programme for Monitoring and Evaluation of the Long-Range Transmission of Air Pollutants in Europe (EMEP) may provide a complete reliable picture of the effect of anthropogenic emissions on soil quality and create a foundation of optimum environmental policy and activities in this field.