The Concrete Degradation Caused by Ammonium Chloride Present in Coke Wastewater

Barbara Słomka-Słupik

doi:10.1007/978-3-030-51210-1_78

The Concrete Degradation Caused by Ammonium Chloride Present in Coke Wastewater

Barbara Słomka-Słupik

Department of Building Structures (RB/RB2)

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

NH₄⁺ and Cl⁻ ions are present in coke sewage and are suspected of causing devastating concrete destruction of wastewater tanks. The corrosive immersion in NH₄Cl water solution of hardened pastes made from 3 different cements was performed. SEM and XRD analyses were used to determine the depth of the attack and trace the microstructural and crystalline phase evolutions. The main effect was revealed to be high porosity near the external surface and at different locations of damage fronts. Thanks to the biggest portlandite content, hardened cement paste of CEM I proved to be the most durable. CEM III underwent the slowest changes, but to the greatest extent.

Original language	English
Title of host publication	Recent Advances in Environmental Science from the Euro-Mediterranean and Surrounding Regions - Proceedings of 2nd Euro-Mediterranean Conference for Environmental Integration, EMCEI-2 2019
Editors	Mohamed Ksibi, Achraf Ghorbal, Sudip Chakraborty, Helder I. Chaminé, Maurizio Barbieri, Giulia Guerriero, Olfa Hentati, Abdelazim Negm, Anthony Lehmann, Jörg Römbke, Armando Costa Duarte, Elena Xoplaki, Nabil Khélifi, Gilles Colinet, João Miguel Dias, Imed Gargouri, Eric D. Van Hullebusch, Benigno Sánchez Cabrero, Settimio Ferlisi, Chedly Tizaoui, Amjad Kallel, Sami Rtimi, Sandeep Panda, Philippe Michaud, Jaya Narayana Sahu, Mongi Seffen, Vincenzo Naddeo
Publisher	Springer Science and Business Media Deutschland GmbH
Pages	493-497
Number of pages	5
ISBN (Print)	9783030512095
DOIs	https://doi.org/10.1007/978-3-030-51210-1_78
Publication status	Published - 2021
Event	2nd Euro-Mediterranean Conference on Environmental Integration, EMCEI 2019 - Sousse, Tunisia Duration: 10 Oct 2019 → 13 Oct 2019

Publication series

Name	Environmental Science and Engineering
ISSN (Print)	1863-5520
ISSN (Electronic)	1863-5539

Conference

Conference	2nd Euro-Mediterranean Conference on Environmental Integration, EMCEI 2019
Country/Territory	Tunisia
City	Sousse
Period	10/10/19 → 13/10/19

Keywords

Concrete degradation
Crystalline phases changes
Leaks
NHCl
Porosity
Sewage

ASJC Scopus subject areas

Environmental Engineering
Information Systems

Access to Document

10.1007/978-3-030-51210-1_78

Cite this

Słomka-Słupik, B. (2021). The Concrete Degradation Caused by Ammonium Chloride Present in Coke Wastewater. In M. Ksibi, A. Ghorbal, S. Chakraborty, H. I. Chaminé, M. Barbieri, G. Guerriero, O. Hentati, A. Negm, A. Lehmann, J. Römbke, A. Costa Duarte, E. Xoplaki, N. Khélifi, G. Colinet, J. Miguel Dias, I. Gargouri, E. D. Van Hullebusch, B. Sánchez Cabrero, S. Ferlisi, C. Tizaoui, A. Kallel, S. Rtimi, S. Panda, P. Michaud, J. N. Sahu, M. Seffen, ... V. Naddeo (Eds.), Recent Advances in Environmental Science from the Euro-Mediterranean and Surrounding Regions - Proceedings of 2nd Euro-Mediterranean Conference for Environmental Integration, EMCEI-2 2019 (pp. 493-497). (Environmental Science and Engineering). Springer Science and Business Media Deutschland GmbH. https://doi.org/10.1007/978-3-030-51210-1_78

Słomka-Słupik, Barbara. / The Concrete Degradation Caused by Ammonium Chloride Present in Coke Wastewater. Recent Advances in Environmental Science from the Euro-Mediterranean and Surrounding Regions - Proceedings of 2nd Euro-Mediterranean Conference for Environmental Integration, EMCEI-2 2019. editor / Mohamed Ksibi ; Achraf Ghorbal ; Sudip Chakraborty ; Helder I. Chaminé ; Maurizio Barbieri ; Giulia Guerriero ; Olfa Hentati ; Abdelazim Negm ; Anthony Lehmann ; Jörg Römbke ; Armando Costa Duarte ; Elena Xoplaki ; Nabil Khélifi ; Gilles Colinet ; João Miguel Dias ; Imed Gargouri ; Eric D. Van Hullebusch ; Benigno Sánchez Cabrero ; Settimio Ferlisi ; Chedly Tizaoui ; Amjad Kallel ; Sami Rtimi ; Sandeep Panda ; Philippe Michaud ; Jaya Narayana Sahu ; Mongi Seffen ; Vincenzo Naddeo. Springer Science and Business Media Deutschland GmbH, 2021. pp. 493-497 (Environmental Science and Engineering).

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title = "The Concrete Degradation Caused by Ammonium Chloride Present in Coke Wastewater",

abstract = "NH4+ and Cl− ions are present in coke sewage and are suspected of causing devastating concrete destruction of wastewater tanks. The corrosive immersion in NH4Cl water solution of hardened pastes made from 3 different cements was performed. SEM and XRD analyses were used to determine the depth of the attack and trace the microstructural and crystalline phase evolutions. The main effect was revealed to be high porosity near the external surface and at different locations of damage fronts. Thanks to the biggest portlandite content, hardened cement paste of CEM I proved to be the most durable. CEM III underwent the slowest changes, but to the greatest extent.",

keywords = "Concrete degradation, Crystalline phases changes, Leaks, NHCl, Porosity, Sewage",

author = "Barbara S{\l}omka-S{\l}upik",

note = "Publisher Copyright: {\textcopyright} 2021, The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Switzerland AG.; 2nd Euro-Mediterranean Conference on Environmental Integration, EMCEI 2019 ; Conference date: 10-10-2019 Through 13-10-2019",

year = "2021",

doi = "10.1007/978-3-030-51210-1\_78",

language = "English",

isbn = "9783030512095",

series = "Environmental Science and Engineering",

publisher = "Springer Science and Business Media Deutschland GmbH",

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booktitle = "Recent Advances in Environmental Science from the Euro-Mediterranean and Surrounding Regions - Proceedings of 2nd Euro-Mediterranean Conference for Environmental Integration, EMCEI-2 2019",

address = "Germany",

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Słomka-Słupik, B 2021, The Concrete Degradation Caused by Ammonium Chloride Present in Coke Wastewater. in M Ksibi, A Ghorbal, S Chakraborty, HI Chaminé, M Barbieri, G Guerriero, O Hentati, A Negm, A Lehmann, J Römbke, A Costa Duarte, E Xoplaki, N Khélifi, G Colinet, J Miguel Dias, I Gargouri, ED Van Hullebusch, B Sánchez Cabrero, S Ferlisi, C Tizaoui, A Kallel, S Rtimi, S Panda, P Michaud, JN Sahu, M Seffen & V Naddeo (eds), Recent Advances in Environmental Science from the Euro-Mediterranean and Surrounding Regions - Proceedings of 2nd Euro-Mediterranean Conference for Environmental Integration, EMCEI-2 2019. Environmental Science and Engineering, Springer Science and Business Media Deutschland GmbH, pp. 493-497, 2nd Euro-Mediterranean Conference on Environmental Integration, EMCEI 2019, Sousse, Tunisia, 10/10/19. https://doi.org/10.1007/978-3-030-51210-1_78

The Concrete Degradation Caused by Ammonium Chloride Present in Coke Wastewater. / Słomka-Słupik, Barbara.
Recent Advances in Environmental Science from the Euro-Mediterranean and Surrounding Regions - Proceedings of 2nd Euro-Mediterranean Conference for Environmental Integration, EMCEI-2 2019. ed. / Mohamed Ksibi; Achraf Ghorbal; Sudip Chakraborty; Helder I. Chaminé; Maurizio Barbieri; Giulia Guerriero; Olfa Hentati; Abdelazim Negm; Anthony Lehmann; Jörg Römbke; Armando Costa Duarte; Elena Xoplaki; Nabil Khélifi; Gilles Colinet; João Miguel Dias; Imed Gargouri; Eric D. Van Hullebusch; Benigno Sánchez Cabrero; Settimio Ferlisi; Chedly Tizaoui; Amjad Kallel; Sami Rtimi; Sandeep Panda; Philippe Michaud; Jaya Narayana Sahu; Mongi Seffen; Vincenzo Naddeo. Springer Science and Business Media Deutschland GmbH, 2021. p. 493-497 (Environmental Science and Engineering).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - The Concrete Degradation Caused by Ammonium Chloride Present in Coke Wastewater

AU - Słomka-Słupik, Barbara

PY - 2021

Y1 - 2021

N2 - NH4+ and Cl− ions are present in coke sewage and are suspected of causing devastating concrete destruction of wastewater tanks. The corrosive immersion in NH4Cl water solution of hardened pastes made from 3 different cements was performed. SEM and XRD analyses were used to determine the depth of the attack and trace the microstructural and crystalline phase evolutions. The main effect was revealed to be high porosity near the external surface and at different locations of damage fronts. Thanks to the biggest portlandite content, hardened cement paste of CEM I proved to be the most durable. CEM III underwent the slowest changes, but to the greatest extent.

AB - NH4+ and Cl− ions are present in coke sewage and are suspected of causing devastating concrete destruction of wastewater tanks. The corrosive immersion in NH4Cl water solution of hardened pastes made from 3 different cements was performed. SEM and XRD analyses were used to determine the depth of the attack and trace the microstructural and crystalline phase evolutions. The main effect was revealed to be high porosity near the external surface and at different locations of damage fronts. Thanks to the biggest portlandite content, hardened cement paste of CEM I proved to be the most durable. CEM III underwent the slowest changes, but to the greatest extent.

KW - Concrete degradation

KW - Crystalline phases changes

KW - Leaks

KW - NHCl

KW - Porosity

KW - Sewage

UR - https://www.scopus.com/pages/publications/85106188013

U2 - 10.1007/978-3-030-51210-1_78

DO - 10.1007/978-3-030-51210-1_78

M3 - Conference contribution

AN - SCOPUS:85106188013

SN - 9783030512095

T3 - Environmental Science and Engineering

SP - 493

EP - 497

BT - Recent Advances in Environmental Science from the Euro-Mediterranean and Surrounding Regions - Proceedings of 2nd Euro-Mediterranean Conference for Environmental Integration, EMCEI-2 2019

A2 - Ksibi, Mohamed

A2 - Ghorbal, Achraf

A2 - Chakraborty, Sudip

A2 - Chaminé, Helder I.

A2 - Barbieri, Maurizio

A2 - Guerriero, Giulia

A2 - Hentati, Olfa

A2 - Negm, Abdelazim

A2 - Lehmann, Anthony

A2 - Römbke, Jörg

A2 - Costa Duarte, Armando

A2 - Xoplaki, Elena

A2 - Khélifi, Nabil

A2 - Colinet, Gilles

A2 - Miguel Dias, João

A2 - Gargouri, Imed

A2 - Van Hullebusch, Eric D.

A2 - Sánchez Cabrero, Benigno

A2 - Ferlisi, Settimio

A2 - Tizaoui, Chedly

A2 - Kallel, Amjad

A2 - Rtimi, Sami

A2 - Panda, Sandeep

A2 - Michaud, Philippe

A2 - Sahu, Jaya Narayana

A2 - Seffen, Mongi

A2 - Naddeo, Vincenzo

PB - Springer Science and Business Media Deutschland GmbH

T2 - 2nd Euro-Mediterranean Conference on Environmental Integration, EMCEI 2019

Y2 - 10 October 2019 through 13 October 2019

ER -

Słomka-Słupik B. The Concrete Degradation Caused by Ammonium Chloride Present in Coke Wastewater. In Ksibi M, Ghorbal A, Chakraborty S, Chaminé HI, Barbieri M, Guerriero G, Hentati O, Negm A, Lehmann A, Römbke J, Costa Duarte A, Xoplaki E, Khélifi N, Colinet G, Miguel Dias J, Gargouri I, Van Hullebusch ED, Sánchez Cabrero B, Ferlisi S, Tizaoui C, Kallel A, Rtimi S, Panda S, Michaud P, Sahu JN, Seffen M, Naddeo V, editors, Recent Advances in Environmental Science from the Euro-Mediterranean and Surrounding Regions - Proceedings of 2nd Euro-Mediterranean Conference for Environmental Integration, EMCEI-2 2019. Springer Science and Business Media Deutschland GmbH. 2021. p. 493-497. (Environmental Science and Engineering). doi: 10.1007/978-3-030-51210-1_78

The Concrete Degradation Caused by Ammonium Chloride Present in Coke Wastewater

Abstract

Publication series

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Keywords

ASJC Scopus subject areas

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