Synthesis of functional polycarbonates by copolymerization of carbon dioxide with allyl glycidyl ether

Jan Łukaszczyk; Katarzyna Jaszcz; Witold Kuran; Tomasz Listos

doi:10.1002/1521-3927(20000701)21:11<754::AID-MARC754>3.0.CO;2-O

Synthesis of functional polycarbonates by copolymerization of carbon dioxide with allyl glycidyl ether

Jan Łukaszczyk
, Katarzyna Jaszcz
, Witold Kuran
, Tomasz Listos

Department of Physical Chemistry and Technology of Polymers (RCH/RCH4)

Silesian University of Technology
Warsaw University of Technology

Research output: Contribution to journal › Article › peer-review

47 Citations (Scopus)

Abstract

Functional aliphatic polycarbonate was synthesized by copolymerization of carbon dioxide and allyl glycidyl ether in the presence of a catalyst system based on ZnEt₂ and pyrogallol at a molar ratio of 2:1. The polycarbonate obtained was oxidized with m-chloroperbenzoic acid to give poly(epoxycarbonate). These polymers were degraded in an aqueous buffer of pH 7.4 at 37°C. Hydrolytic degradation was monitored by determination of the weight loss.

Original language	English
Pages (from-to)	754-757
Number of pages	4
Journal	Macromolecular Rapid Communications
Volume	21
Issue number	11
DOIs	https://doi.org/10.1002/1521-3927(20000701)21:11<754::AID-MARC754>3.0.CO;2-O
Publication status	Published - 31 Jul 2000

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Materials Chemistry

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10.1002/1521-3927(20000701)21:11<754::AID-MARC754>3.0.CO;2-O

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abstract = "Functional aliphatic polycarbonate was synthesized by copolymerization of carbon dioxide and allyl glycidyl ether in the presence of a catalyst system based on ZnEt2 and pyrogallol at a molar ratio of 2:1. The polycarbonate obtained was oxidized with m-chloroperbenzoic acid to give poly(epoxycarbonate). These polymers were degraded in an aqueous buffer of pH 7.4 at 37°C. Hydrolytic degradation was monitored by determination of the weight loss.",

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T1 - Synthesis of functional polycarbonates by copolymerization of carbon dioxide with allyl glycidyl ether

AU - Łukaszczyk, Jan

AU - Jaszcz, Katarzyna

AU - Kuran, Witold

AU - Listos, Tomasz

PY - 2000/7/31

Y1 - 2000/7/31

N2 - Functional aliphatic polycarbonate was synthesized by copolymerization of carbon dioxide and allyl glycidyl ether in the presence of a catalyst system based on ZnEt2 and pyrogallol at a molar ratio of 2:1. The polycarbonate obtained was oxidized with m-chloroperbenzoic acid to give poly(epoxycarbonate). These polymers were degraded in an aqueous buffer of pH 7.4 at 37°C. Hydrolytic degradation was monitored by determination of the weight loss.

AB - Functional aliphatic polycarbonate was synthesized by copolymerization of carbon dioxide and allyl glycidyl ether in the presence of a catalyst system based on ZnEt2 and pyrogallol at a molar ratio of 2:1. The polycarbonate obtained was oxidized with m-chloroperbenzoic acid to give poly(epoxycarbonate). These polymers were degraded in an aqueous buffer of pH 7.4 at 37°C. Hydrolytic degradation was monitored by determination of the weight loss.

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U2 - 10.1002/1521-3927(20000701)21:11<754::AID-MARC754>3.0.CO;2-O

DO - 10.1002/1521-3927(20000701)21:11<754::AID-MARC754>3.0.CO;2-O

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JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

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ER -

Synthesis of functional polycarbonates by copolymerization of carbon dioxide with allyl glycidyl ether

Abstract

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