Abstract
The synthesis of dialkyl peroxides from alkyl hydroperoxides and alkyl bromides in the presence of polymer-supported phase-transfer catalysts has been investigated. It was revealed that polymer-bound quaternary ammonium and polyethylene glycol catalysts were more active than their soluble forms. High yields (60-92%) of the products were obtained. The catalyst could be recycled several times with no appreciable loss of activity.
| Original language | English |
|---|---|
| Pages (from-to) | 85-90 |
| Number of pages | 6 |
| Journal | Applied Catalysis A: General |
| Volume | 309 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 17 Jul 2006 |
Keywords
- Dialkyl peroxides
- Hydroperoxides
- Polymer-supported phase-transfer catalysts
- Triphase catalysis
ASJC Scopus subject areas
- Catalysis
- Process Chemistry and Technology
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