TY - GEN
T1 - Synthesis by Stille cross-coupling procedure and electrochemical characterization of branched polymers based on substituted 1,3,5-triarylbenzenes
AU - Idzik, Krzysztof R.
AU - Beckert, Rainer
AU - Tauscher, Eric
AU - Ledwon, Przemyslaw
AU - Golba, Sylwia
AU - Lapkowski, Mieczyslaw
AU - Rapta, Peter
AU - Dunsche, Lothar
AU - Frydel, Jaroslaw
PY - 2011
Y1 - 2011
N2 - A series of various substituted 1,3,5-triarylbenzenes, 2,4,6-triaryl-1- phenoles, 1,3,5-triaryl-1-methoxybenzenes and 2,4,6-triaryl-1,3,5- trimethoxybenzenes were synthesized by a Stille cross-coupling procedure. Their structures were confirmed by 1H NMR, 13C NMR, and elemental analysis. Containing thienyl, furyl and EDOT groups polymers obtained in the process of electropolymerization could be carefully considered as a building material in a wide range of organic-electronic devices. We compare properties of monomers and related polymers depending on aryls moieties and their influence of hydroxyl and methoxyl groups attached to the central benzene core.
AB - A series of various substituted 1,3,5-triarylbenzenes, 2,4,6-triaryl-1- phenoles, 1,3,5-triaryl-1-methoxybenzenes and 2,4,6-triaryl-1,3,5- trimethoxybenzenes were synthesized by a Stille cross-coupling procedure. Their structures were confirmed by 1H NMR, 13C NMR, and elemental analysis. Containing thienyl, furyl and EDOT groups polymers obtained in the process of electropolymerization could be carefully considered as a building material in a wide range of organic-electronic devices. We compare properties of monomers and related polymers depending on aryls moieties and their influence of hydroxyl and methoxyl groups attached to the central benzene core.
KW - Cyclic voltammetry
KW - Electrochemical polymerization
KW - Hyperbranched polymers
KW - Stille coupling procedure
UR - https://www.scopus.com/pages/publications/78649976871
U2 - 10.4028/www.scientific.net/MSF.663-665.876
DO - 10.4028/www.scientific.net/MSF.663-665.876
M3 - Conference contribution
AN - SCOPUS:78649976871
SN - 0878492119
SN - 9780878492114
T3 - Materials Science Forum
SP - 876
EP - 879
BT - Optoelectronic Materials
A2 - Huang, Yuan Ming
PB - Trans Tech Publications Ltd.
ER -