Synthesis and Structural Characterization of Novel Urethane-Dimethacrylate Monomer with Two Quaternary Ammonium Groups †

Patryk Drejka; Marta Chrószcz-Porębska; Izabela Barszczewska-Rybarek

doi:10.3390/ASEC2023-15348

Synthesis and Structural Characterization of Novel Urethane-Dimethacrylate Monomer with Two Quaternary Ammonium Groups †

Patryk Drejka
, Marta Chrószcz-Porębska
, Izabela Barszczewska-Rybarek

Silesian University of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

Composite restorative materials with dimethacrylathe matrices are commonly used as dental fillings. They have good usable properties; however, they lack antibacterial activity. They may also promote secondary caries. A solution to that problem could be the application of monomers with microbiologically active quaternary ammonium groups. This research aimed at the synthesis of a new urethane-dimethacrylate monomer with a 1,3-bis(2-isocyanatopropan-2-yl)benzene (TMXDI) core, as well as two arms with quaternary ammonium group with the decyl subsistent. The structure of the obtained monomer was confirmed via FTIR and ¹H and ¹³C NMR spectroscopies.

Original language	English
Article number	285
Journal	Engineering Proceedings
Volume	56
Issue number	1
DOIs	https://doi.org/10.3390/ASEC2023-15348
Publication status	Published - 2023

Keywords

photocurable dental resins
quaternary ammonium groups
urethane-dimethacrylate monomer

ASJC Scopus subject areas

Biomedical Engineering
Mechanical Engineering
Industrial and Manufacturing Engineering
Electrical and Electronic Engineering

Access to Document

10.3390/ASEC2023-15348

Cite this

@article{d65ec49c14404e4db65df678c1ff3149,

title = "Synthesis and Structural Characterization of Novel Urethane-Dimethacrylate Monomer with Two Quaternary Ammonium Groups †",

abstract = "Composite restorative materials with dimethacrylathe matrices are commonly used as dental fillings. They have good usable properties; however, they lack antibacterial activity. They may also promote secondary caries. A solution to that problem could be the application of monomers with microbiologically active quaternary ammonium groups. This research aimed at the synthesis of a new urethane-dimethacrylate monomer with a 1,3-bis(2-isocyanatopropan-2-yl)benzene (TMXDI) core, as well as two arms with quaternary ammonium group with the decyl subsistent. The structure of the obtained monomer was confirmed via FTIR and 1H and 13C NMR spectroscopies.",

keywords = "photocurable dental resins, quaternary ammonium groups, urethane-dimethacrylate monomer",

author = "Patryk Drejka and Marta Chr{\'o}szcz-Por{\c e}bska and Izabela Barszczewska-Rybarek",

note = "Publisher Copyright: {\textcopyright} 2023 by the authors.",

year = "2023",

doi = "10.3390/ASEC2023-15348",

language = "English",

volume = "56",

journal = "Engineering Proceedings",

issn = "2673-4591",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

number = "1",

}

TY - JOUR

T1 - Synthesis and Structural Characterization of Novel Urethane-Dimethacrylate Monomer with Two Quaternary Ammonium Groups †

AU - Drejka, Patryk

AU - Chrószcz-Porębska, Marta

AU - Barszczewska-Rybarek, Izabela

PY - 2023

Y1 - 2023

N2 - Composite restorative materials with dimethacrylathe matrices are commonly used as dental fillings. They have good usable properties; however, they lack antibacterial activity. They may also promote secondary caries. A solution to that problem could be the application of monomers with microbiologically active quaternary ammonium groups. This research aimed at the synthesis of a new urethane-dimethacrylate monomer with a 1,3-bis(2-isocyanatopropan-2-yl)benzene (TMXDI) core, as well as two arms with quaternary ammonium group with the decyl subsistent. The structure of the obtained monomer was confirmed via FTIR and 1H and 13C NMR spectroscopies.

AB - Composite restorative materials with dimethacrylathe matrices are commonly used as dental fillings. They have good usable properties; however, they lack antibacterial activity. They may also promote secondary caries. A solution to that problem could be the application of monomers with microbiologically active quaternary ammonium groups. This research aimed at the synthesis of a new urethane-dimethacrylate monomer with a 1,3-bis(2-isocyanatopropan-2-yl)benzene (TMXDI) core, as well as two arms with quaternary ammonium group with the decyl subsistent. The structure of the obtained monomer was confirmed via FTIR and 1H and 13C NMR spectroscopies.

KW - photocurable dental resins

KW - quaternary ammonium groups

KW - urethane-dimethacrylate monomer

UR - https://www.scopus.com/pages/publications/85186399221

U2 - 10.3390/ASEC2023-15348

DO - 10.3390/ASEC2023-15348

M3 - Article

AN - SCOPUS:85186399221

SN - 2673-4591

VL - 56

JO - Engineering Proceedings

JF - Engineering Proceedings

IS - 1

M1 - 285

ER -

Synthesis and Structural Characterization of Novel Urethane-Dimethacrylate Monomer with Two Quaternary Ammonium Groups †

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this