Rhenium(i) terpyridine complexes-synthesis, photophysical properties and application in organic light emitting devices

Tomasz Klemens; Anna ͆witlicka-Olszewska; Barbara Machura; Marzena Grucela; Ewa Schab-Balcerzak; Karolina Smolarek; Sebastian Mackowski; Agata Szlapa; Slawomir Kula; Stanisław Krompiec; Piotr Lodowski; Anna Chrobok

doi:10.1039/c5dt04093k

Rhenium(i) terpyridine complexes-synthesis, photophysical properties and application in organic light emitting devices

Tomasz Klemens
, Anna ͆witlicka-Olszewska
, Barbara Machura
, Marzena Grucela
, Ewa Schab-Balcerzak
, Karolina Smolarek
, Sebastian Mackowski
, Agata Szlapa
, Slawomir Kula
, Stanisław Krompiec
, Piotr Lodowski
, Anna Chrobok

Department of Chemical Organic Technology and Petrochemistry (RCH/RCH5)

University of Silesia in Katowice
Polish Academy of Sciences
Nicolaus Copernicus University in Toruń

Research output: Contribution to journal › Article › peer-review

63 Citations (Scopus)

Abstract

Six new Re(i) complexes of the general formula [ReCl(CO)₃(4′-R-terpy-κ²N)] with 2,2′:6′,2′′-terpyridine-based ligands have been synthesized and characterized by IR, NMR (¹H and ¹³C), UV-Vis spectroscopy and single crystal X-ray analysis. The luminescent properties of [ReCl(CO)₃(4′-R-terpy-κ²N)] were studied in solution and solid state, at 298 and 77 K, respectively. To obtain detailed insight into the electronic structures and spectroscopic properties of [ReCl(CO)₃(4′-R-terpy-κ²N)], the density functional theory (DFT) and time-dependent DFT (TD-DFT) calculations were performed. Also, the suitability of this class of materials for being applied in organic light emitting diodes (OLEDs) has been preliminarily tested.

Original language	English
Pages (from-to)	1746-1762
Number of pages	17
Journal	Dalton Transactions
Volume	45
Issue number	4
DOIs	https://doi.org/10.1039/c5dt04093k
Publication status	Published - 2016

ASJC Scopus subject areas

Inorganic Chemistry

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Klemens, T., ͆witlicka-Olszewska, A., Machura, B., Grucela, M., Schab-Balcerzak, E., Smolarek, K., Mackowski, S., Szlapa, A., Kula, S., Krompiec, S., Lodowski, P., & Chrobok, A. (2016). Rhenium(i) terpyridine complexes-synthesis, photophysical properties and application in organic light emitting devices. Dalton Transactions, 45(4), 1746-1762. https://doi.org/10.1039/c5dt04093k

@article{14afda80b5d74408844ceb6ab2443b90,

title = "Rhenium(i) terpyridine complexes-synthesis, photophysical properties and application in organic light emitting devices",

abstract = "Six new Re(i) complexes of the general formula [ReCl(CO)3(4′-R-terpy-κ2N)] with 2,2′:6′,2′′-terpyridine-based ligands have been synthesized and characterized by IR, NMR (1H and 13C), UV-Vis spectroscopy and single crystal X-ray analysis. The luminescent properties of [ReCl(CO)3(4′-R-terpy-κ2N)] were studied in solution and solid state, at 298 and 77 K, respectively. To obtain detailed insight into the electronic structures and spectroscopic properties of [ReCl(CO)3(4′-R-terpy-κ2N)], the density functional theory (DFT) and time-dependent DFT (TD-DFT) calculations were performed. Also, the suitability of this class of materials for being applied in organic light emitting diodes (OLEDs) has been preliminarily tested.",

author = "Tomasz Klemens and Anna ͆witlicka-Olszewska and Barbara Machura and Marzena Grucela and Ewa Schab-Balcerzak and Karolina Smolarek and Sebastian Mackowski and Agata Szlapa and Slawomir Kula and Stanis{\l}aw Krompiec and Piotr Lodowski and Anna Chrobok",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",

year = "2016",

doi = "10.1039/c5dt04093k",

language = "English",

volume = "45",

pages = "1746--1762",

journal = "Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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Klemens, T, ͆witlicka-Olszewska, A, Machura, B, Grucela, M, Schab-Balcerzak, E, Smolarek, K, Mackowski, S, Szlapa, A, Kula, S, Krompiec, S, Lodowski, P & Chrobok, A 2016, 'Rhenium(i) terpyridine complexes-synthesis, photophysical properties and application in organic light emitting devices', Dalton Transactions, vol. 45, no. 4, pp. 1746-1762. https://doi.org/10.1039/c5dt04093k

TY - JOUR

T1 - Rhenium(i) terpyridine complexes-synthesis, photophysical properties and application in organic light emitting devices

AU - Klemens, Tomasz

AU - ͆witlicka-Olszewska, Anna

AU - Machura, Barbara

AU - Grucela, Marzena

AU - Schab-Balcerzak, Ewa

AU - Smolarek, Karolina

AU - Mackowski, Sebastian

AU - Szlapa, Agata

AU - Kula, Slawomir

AU - Krompiec, Stanisław

AU - Lodowski, Piotr

AU - Chrobok, Anna

PY - 2016

Y1 - 2016

N2 - Six new Re(i) complexes of the general formula [ReCl(CO)3(4′-R-terpy-κ2N)] with 2,2′:6′,2′′-terpyridine-based ligands have been synthesized and characterized by IR, NMR (1H and 13C), UV-Vis spectroscopy and single crystal X-ray analysis. The luminescent properties of [ReCl(CO)3(4′-R-terpy-κ2N)] were studied in solution and solid state, at 298 and 77 K, respectively. To obtain detailed insight into the electronic structures and spectroscopic properties of [ReCl(CO)3(4′-R-terpy-κ2N)], the density functional theory (DFT) and time-dependent DFT (TD-DFT) calculations were performed. Also, the suitability of this class of materials for being applied in organic light emitting diodes (OLEDs) has been preliminarily tested.

AB - Six new Re(i) complexes of the general formula [ReCl(CO)3(4′-R-terpy-κ2N)] with 2,2′:6′,2′′-terpyridine-based ligands have been synthesized and characterized by IR, NMR (1H and 13C), UV-Vis spectroscopy and single crystal X-ray analysis. The luminescent properties of [ReCl(CO)3(4′-R-terpy-κ2N)] were studied in solution and solid state, at 298 and 77 K, respectively. To obtain detailed insight into the electronic structures and spectroscopic properties of [ReCl(CO)3(4′-R-terpy-κ2N)], the density functional theory (DFT) and time-dependent DFT (TD-DFT) calculations were performed. Also, the suitability of this class of materials for being applied in organic light emitting diodes (OLEDs) has been preliminarily tested.

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DO - 10.1039/c5dt04093k

M3 - Article

AN - SCOPUS:84955494524

SN - 1477-9226

VL - 45

SP - 1746

EP - 1762

JO - Dalton Transactions

JF - Dalton Transactions

IS - 4

ER -

Rhenium(i) terpyridine complexes-synthesis, photophysical properties and application in organic light emitting devices

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