Preparation of poly(isothianaphthene) from 2,5-bis(trialkylsilyl)isothianaphthenes

M. Łapkowski; R. Kiebooms; A. Proń; O. Chauvet; J. Gelan; D. Vanderzande; S. Lefrant

doi:10.1016/s0379-6779(97)80808-9

Preparation of poly(isothianaphthene) from 2,5-bis(trialkylsilyl)isothianaphthenes

M. Łapkowski
, R. Kiebooms
, A. Proń
, O. Chauvet
, J. Gelan
, D. Vanderzande
, S. Lefrant

Department of Physical Chemistry and Technology of Polymers (RCH/RCH4)

University of Bielsko-Biala
Hasselt University
AGH University of Krakow
Warsaw University of Technology
Nantes Université

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

It is demonstrated that the anodic oxidation of 2,5-bis(tert-butyldimethylsilyl) isothianaphthene in Bu₄NBF₄/nitrobenzene electrolyte results in the formation of poly(isothianaphthene) film with an average polymerization degree of 20. Disilylated isothianaphthene dimer and trimer do not polymerize in this electrolyte giving upon anodic oxidation stable radical cations and dications.

Original language	English
Pages (from-to)	413-414
Number of pages	2
Journal	Synthetic Metals
Volume	84
Issue number	1-3
DOIs	https://doi.org/10.1016/s0379-6779(97)80808-9
Publication status	Published - Jan 1997

Keywords

Electrochemistry
Poly(isothianaphthene)
Raman spectroelectrochemistry
Spectroelectrochemistry

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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10.1016/s0379-6779(97)80808-9

Cite this

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title = "Preparation of poly(isothianaphthene) from 2,5-bis(trialkylsilyl)isothianaphthenes",

abstract = "It is demonstrated that the anodic oxidation of 2,5-bis(tert-butyldimethylsilyl) isothianaphthene in Bu4NBF4/nitrobenzene electrolyte results in the formation of poly(isothianaphthene) film with an average polymerization degree of 20. Disilylated isothianaphthene dimer and trimer do not polymerize in this electrolyte giving upon anodic oxidation stable radical cations and dications.",

keywords = "Electrochemistry, Poly(isothianaphthene), Raman spectroelectrochemistry, Spectroelectrochemistry",

author = "M. {\L}apkowski and R. Kiebooms and A. Pro{\'n} and O. Chauvet and J. Gelan and D. Vanderzande and S. Lefrant",

year = "1997",

month = jan,

doi = "10.1016/s0379-6779(97)80808-9",

language = "English",

volume = "84",

pages = "413--414",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier B.V.",

number = "1-3",

}

TY - JOUR

T1 - Preparation of poly(isothianaphthene) from 2,5-bis(trialkylsilyl)isothianaphthenes

AU - Łapkowski, M.

AU - Kiebooms, R.

AU - Proń, A.

AU - Chauvet, O.

AU - Gelan, J.

AU - Vanderzande, D.

AU - Lefrant, S.

PY - 1997/1

Y1 - 1997/1

N2 - It is demonstrated that the anodic oxidation of 2,5-bis(tert-butyldimethylsilyl) isothianaphthene in Bu4NBF4/nitrobenzene electrolyte results in the formation of poly(isothianaphthene) film with an average polymerization degree of 20. Disilylated isothianaphthene dimer and trimer do not polymerize in this electrolyte giving upon anodic oxidation stable radical cations and dications.

AB - It is demonstrated that the anodic oxidation of 2,5-bis(tert-butyldimethylsilyl) isothianaphthene in Bu4NBF4/nitrobenzene electrolyte results in the formation of poly(isothianaphthene) film with an average polymerization degree of 20. Disilylated isothianaphthene dimer and trimer do not polymerize in this electrolyte giving upon anodic oxidation stable radical cations and dications.

KW - Electrochemistry

KW - Poly(isothianaphthene)

KW - Raman spectroelectrochemistry

KW - Spectroelectrochemistry

UR - https://www.scopus.com/pages/publications/0030714793

U2 - 10.1016/s0379-6779(97)80808-9

DO - 10.1016/s0379-6779(97)80808-9

M3 - Article

AN - SCOPUS:0030714793

SN - 0379-6779

VL - 84

SP - 413

EP - 414

JO - Synthetic Metals

JF - Synthetic Metals

IS - 1-3

ER -

Preparation of poly(isothianaphthene) from 2,5-bis(trialkylsilyl)isothianaphthenes

Abstract

Keywords

ASJC Scopus subject areas

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