Polymer-supported N-hydroxyphthalimide as catalyst for toluene and p-methoxytoluene aerobic oxidation

Kornela Kasperczyk; Beata Orlinska; Ewa Witek; Piotr Łątka; Jan Zawadiak; Leonard Proniewicz

doi:10.1007/s10562-015-1578-4

Polymer-supported N-hydroxyphthalimide as catalyst for toluene and p-methoxytoluene aerobic oxidation

Kornela Kasperczyk
, Beata Orlinska
, Ewa Witek
, Piotr Łątka
, Jan Zawadiak
, Leonard Proniewicz

Department of Chemical Organic Technology and Petrochemistry (RCH/RCH5)

Silesian University of Technology
Jagiellonian University in Kraków

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

In the present study, N-hydroxyphthalimide (NHPI) was successfully immobilized on (aminomethyl) polystyrene and (chloromethyl) polystyrene via amide or ester bonds. The obtained polymer-supported NHPIs have demonstrated catalytic activity for the aerobic oxidation of toluene and p-methoxytoluene. The oxidations were performed using cobalt(II) salts as co-catalysts, in acetic acid as solvent or in more environmentally acceptable solventfree system. The possibility of recovery and recycling of the obtained polymer-supported NHPIs was reported.

Original language	English
Pages (from-to)	1856-1867
Number of pages	12
Journal	Catalysis Letters
Volume	145
Issue number	10
DOIs	https://doi.org/10.1007/s10562-015-1578-4
Publication status	Published - Oct 2015

Keywords

N-Hydroxyphthalimide
Oxidation
P-Methoxytoluene
Polymer-supported catalysts
Toluene

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1007/s10562-015-1578-4

Cite this

@article{ad7254abf32a46e58583654cec2d0809,

title = "Polymer-supported N-hydroxyphthalimide as catalyst for toluene and p-methoxytoluene aerobic oxidation",

abstract = "In the present study, N-hydroxyphthalimide (NHPI) was successfully immobilized on (aminomethyl) polystyrene and (chloromethyl) polystyrene via amide or ester bonds. The obtained polymer-supported NHPIs have demonstrated catalytic activity for the aerobic oxidation of toluene and p-methoxytoluene. The oxidations were performed using cobalt(II) salts as co-catalysts, in acetic acid as solvent or in more environmentally acceptable solventfree system. The possibility of recovery and recycling of the obtained polymer-supported NHPIs was reported.",

keywords = "N-Hydroxyphthalimide, Oxidation, P-Methoxytoluene, Polymer-supported catalysts, Toluene",

author = "Kornela Kasperczyk and Beata Orlinska and Ewa Witek and Piotr {\L}{\c a}tka and Jan Zawadiak and Leonard Proniewicz",

note = "Publisher Copyright: {\textcopyright} Springer Science+Business Media New York 2015.",

year = "2015",

month = oct,

doi = "10.1007/s10562-015-1578-4",

language = "English",

volume = "145",

pages = "1856--1867",

journal = "Catalysis Letters",

issn = "1011-372X",

publisher = "Kluwer Academic Publishers",

number = "10",

}

TY - JOUR

T1 - Polymer-supported N-hydroxyphthalimide as catalyst for toluene and p-methoxytoluene aerobic oxidation

AU - Kasperczyk, Kornela

AU - Orlinska, Beata

AU - Witek, Ewa

AU - Łątka, Piotr

AU - Zawadiak, Jan

AU - Proniewicz, Leonard

N1 - Publisher Copyright: © Springer Science+Business Media New York 2015.

PY - 2015/10

Y1 - 2015/10

N2 - In the present study, N-hydroxyphthalimide (NHPI) was successfully immobilized on (aminomethyl) polystyrene and (chloromethyl) polystyrene via amide or ester bonds. The obtained polymer-supported NHPIs have demonstrated catalytic activity for the aerobic oxidation of toluene and p-methoxytoluene. The oxidations were performed using cobalt(II) salts as co-catalysts, in acetic acid as solvent or in more environmentally acceptable solventfree system. The possibility of recovery and recycling of the obtained polymer-supported NHPIs was reported.

AB - In the present study, N-hydroxyphthalimide (NHPI) was successfully immobilized on (aminomethyl) polystyrene and (chloromethyl) polystyrene via amide or ester bonds. The obtained polymer-supported NHPIs have demonstrated catalytic activity for the aerobic oxidation of toluene and p-methoxytoluene. The oxidations were performed using cobalt(II) salts as co-catalysts, in acetic acid as solvent or in more environmentally acceptable solventfree system. The possibility of recovery and recycling of the obtained polymer-supported NHPIs was reported.

KW - N-Hydroxyphthalimide

KW - Oxidation

KW - P-Methoxytoluene

KW - Polymer-supported catalysts

KW - Toluene

UR - https://www.scopus.com/pages/publications/84999116051

U2 - 10.1007/s10562-015-1578-4

DO - 10.1007/s10562-015-1578-4

M3 - Article

AN - SCOPUS:84999116051

SN - 1011-372X

VL - 145

SP - 1856

EP - 1867

JO - Catalysis Letters

JF - Catalysis Letters

IS - 10

ER -

Polymer-supported N-hydroxyphthalimide as catalyst for toluene and p-methoxytoluene aerobic oxidation

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this