Oxidation of cycloalkanes catalysed by N-hydroxyimides in supercritical carbon dioxide

Dawid Lisicki; Beata Orlińska

doi:10.1007/s11696-019-00937-0

Oxidation of cycloalkanes catalysed by N-hydroxyimides in supercritical carbon dioxide

Department of Chemical Organic Technology and Petrochemistry (RCH/RCH5)

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

This paper reports cyclopentane, cyclohexane and cyclooctane oxidation in the presence of N-hydroxyphthalimide or 4-dodecyloxycarbonyl-N-hydroxyphthalimide in combination with Co(II) and Fe(II) salts using O₂/CO₂ mixture (0.5 MPa O₂, 9.5 MPa CO₂). The studies demonstrated that the application of scCO₂ in cyclohexane and cyclooctane oxidation processes results in higher conversion and yield of respective ketone and alcohol in comparison to processes performed using air under pressure (0.7 MPa).

Original language	English
Pages (from-to)	711-716
Number of pages	6
Journal	Chemical Papers
Volume	74
Issue number	2
DOIs	https://doi.org/10.1007/s11696-019-00937-0
Publication status	Published - 1 Feb 2020

Keywords

Carbon dioxide
Cyclohexane
Cyclooctane
Cyclopentane
N-Hydroxyphthalimide
Oxidation

ASJC Scopus subject areas

General Chemistry
Biochemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Materials Chemistry

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10.1007/s11696-019-00937-0

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title = "Oxidation of cycloalkanes catalysed by N-hydroxyimides in supercritical carbon dioxide",

abstract = "This paper reports cyclopentane, cyclohexane and cyclooctane oxidation in the presence of N-hydroxyphthalimide or 4-dodecyloxycarbonyl-N-hydroxyphthalimide in combination with Co(II) and Fe(II) salts using O2/CO2 mixture (0.5 MPa O2, 9.5 MPa CO2). The studies demonstrated that the application of scCO2 in cyclohexane and cyclooctane oxidation processes results in higher conversion and yield of respective ketone and alcohol in comparison to processes performed using air under pressure (0.7 MPa).",

keywords = "Carbon dioxide, Cyclohexane, Cyclooctane, Cyclopentane, N-Hydroxyphthalimide, Oxidation",

author = "Dawid Lisicki and Beata Orli{\'n}ska",

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year = "2020",

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doi = "10.1007/s11696-019-00937-0",

language = "English",

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T1 - Oxidation of cycloalkanes catalysed by N-hydroxyimides in supercritical carbon dioxide

AU - Lisicki, Dawid

AU - Orlińska, Beata

PY - 2020/2/1

Y1 - 2020/2/1

N2 - This paper reports cyclopentane, cyclohexane and cyclooctane oxidation in the presence of N-hydroxyphthalimide or 4-dodecyloxycarbonyl-N-hydroxyphthalimide in combination with Co(II) and Fe(II) salts using O2/CO2 mixture (0.5 MPa O2, 9.5 MPa CO2). The studies demonstrated that the application of scCO2 in cyclohexane and cyclooctane oxidation processes results in higher conversion and yield of respective ketone and alcohol in comparison to processes performed using air under pressure (0.7 MPa).

AB - This paper reports cyclopentane, cyclohexane and cyclooctane oxidation in the presence of N-hydroxyphthalimide or 4-dodecyloxycarbonyl-N-hydroxyphthalimide in combination with Co(II) and Fe(II) salts using O2/CO2 mixture (0.5 MPa O2, 9.5 MPa CO2). The studies demonstrated that the application of scCO2 in cyclohexane and cyclooctane oxidation processes results in higher conversion and yield of respective ketone and alcohol in comparison to processes performed using air under pressure (0.7 MPa).

KW - Carbon dioxide

KW - Cyclohexane

KW - Cyclooctane

KW - Cyclopentane

KW - N-Hydroxyphthalimide

KW - Oxidation

UR - https://www.scopus.com/pages/publications/85074012591

U2 - 10.1007/s11696-019-00937-0

DO - 10.1007/s11696-019-00937-0

M3 - Article

AN - SCOPUS:85074012591

SN - 0366-6352

VL - 74

SP - 711

EP - 716

JO - Chemical Papers

JF - Chemical Papers

IS - 2

ER -

Oxidation of cycloalkanes catalysed by N-hydroxyimides in supercritical carbon dioxide

Abstract

Keywords

ASJC Scopus subject areas

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