On the oxidation of polyaniline in the relaxation process by the voltammetric experiment

Przemyslaw Borys; Mieczyslaw Lapkowski; Jerzy Zak; Zbigniew J. Grzywna

doi:10.1016/j.cplett.2007.08.024

On the oxidation of polyaniline in the relaxation process by the voltammetric experiment

Przemyslaw Borys
, Mieczyslaw Lapkowski
, Jerzy Zak
, Zbigniew J. Grzywna

Department of Physical Chemistry and Technology of Polymers (RCH/RCH4)

Silesian University of Technology

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Some important physical processes represented by the shape of voltammograms of polyaniline in the phase of oxidation are identified and modelled. The main process, i.e. an angular diffusion by which the motion of conducting polymer subunits take place is described and modelled. To fit a molecular picture of the oxidation process a nontrivial random walk of polymer subunits in configurational space of angles has been performed. A very good agreement between theoretical predictions and experimental data has been obtained.

Original language	English
Pages (from-to)	391-394
Number of pages	4
Journal	Chemical Physics Letters
Volume	446
Issue number	4-6
DOIs	https://doi.org/10.1016/j.cplett.2007.08.024
Publication status	Published - 4 Oct 2007

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1016/j.cplett.2007.08.024

Cite this

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abstract = "Some important physical processes represented by the shape of voltammograms of polyaniline in the phase of oxidation are identified and modelled. The main process, i.e. an angular diffusion by which the motion of conducting polymer subunits take place is described and modelled. To fit a molecular picture of the oxidation process a nontrivial random walk of polymer subunits in configurational space of angles has been performed. A very good agreement between theoretical predictions and experimental data has been obtained.",

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AU - Zak, Jerzy

AU - Grzywna, Zbigniew J.

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N2 - Some important physical processes represented by the shape of voltammograms of polyaniline in the phase of oxidation are identified and modelled. The main process, i.e. an angular diffusion by which the motion of conducting polymer subunits take place is described and modelled. To fit a molecular picture of the oxidation process a nontrivial random walk of polymer subunits in configurational space of angles has been performed. A very good agreement between theoretical predictions and experimental data has been obtained.

AB - Some important physical processes represented by the shape of voltammograms of polyaniline in the phase of oxidation are identified and modelled. The main process, i.e. an angular diffusion by which the motion of conducting polymer subunits take place is described and modelled. To fit a molecular picture of the oxidation process a nontrivial random walk of polymer subunits in configurational space of angles has been performed. A very good agreement between theoretical predictions and experimental data has been obtained.

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M3 - Article

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On the oxidation of polyaniline in the relaxation process by the voltammetric experiment

Abstract

ASJC Scopus subject areas

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