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Izopropylonaftaleny - Potencjalne surowce w procesach utleniania

Translated title of the contribution: Isopropylnaphthalenes - A potential feedstock for oxidation processes
  • Jan Zawadiak
  • , Zbigniew Stec
  • , Ulrich Knips
  • , Robert Zellerhoff
  • Silesian University of Technology
  • Rütgers Chemicals AG
  • Rütgers Kureha Solvents GmbH

Research output: Contribution to journalReview articlepeer-review

3 Citations (Scopus)

Abstract

A review with 35 refs. (including Authors' 6 works) covering separation of 2- from 1-isopropylnaphthalene, the latter suppressing oxidation rate, yield and selectivity toward 2-(1-hydroperoxy-1-methylethyl)naphthalene, Authors' kinetic data on oxidation of 1- and 2-isopropylnaphthalene and cumene (the 1- is less prone to oxidation than the 2- by a factor of 10-12; the 2- and cumene are comparable), distillative preparation of 99% pure 2,6-diisopropylnaphthalene, oxidation to 2,6-dicarboxynaphthalenic acid, which involves formation of first mono- and then dihydroperoxide and mono-alcohols, and preparation of 2,6-dihydroxynaphthalene. 2-Iso- and 2,6-diisopropylnaphthalenes can be used to make 2-naphthol, 2-acetylnaphthalene, 2-isopropenylnaphthalene, 2,6-dihydroxynaphthalene and other fine chemicals.

Translated title of the contributionIsopropylnaphthalenes - A potential feedstock for oxidation processes
Original languagePolish
Pages (from-to)388-392
Number of pages5
JournalPrzemysl Chemiczny
Volume82
Issue number6
Publication statusPublished - 2003

ASJC Scopus subject areas

  • General Chemistry
  • General Chemical Engineering

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