Hydrazones containing electron-accepting and electron-donating moieties

D. Gudeika; R. Lygaitis; V. Mimaite; J. V. Grazulevicius; V. Jankauskas; M. Lapkowski; P. Data

doi:10.1016/j.dyepig.2011.02.002

Hydrazones containing electron-accepting and electron-donating moieties

D. Gudeika
, R. Lygaitis
, V. Mimaite
, J. V. Grazulevicius
, V. Jankauskas
, M. Lapkowski
, P. Data

Kaunas University of Technology
Vilnius University
Polish Academy of Sciences

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Hydrazones containing electron-accepting 1,8-naphthalimide species and electron-donating triphenylamino moieties were synthesized and characterized by nuclear magnetic resonance, infrared spectroscopy, and mass spectrometry. Thermal, optical, electrochemical and photophysical properties of the synthesized derivatives were investigated, their, optical and electrochemical band-gap energies and ionization potentials were established. The hydrazones exhibit initial mass loss temperatures in the range of 268-348 °C and can form glasses with glass transition temperatures in the range of 46-142 °C as established by differential scanning calorimetry. Room temperature time-of-flight hole mobilities in the solid solutions of the derivatives in the polymeric host bisphenol-Z polycarbonate (50%) exceeded 10^-5 cm ²/V s at high applied electric fields.

Original language	English
Pages (from-to)	13-19
Number of pages	7
Journal	Dyes and Pigments
Volume	91
Issue number	1
DOIs	https://doi.org/10.1016/j.dyepig.2011.02.002
Publication status	Published - Oct 2011

Keywords

Charge mobility
Electron-accepting
Electron-donating
Glass-forming
Hydrazone
Ionization potential

ASJC Scopus subject areas

General Chemical Engineering
Process Chemistry and Technology

Access to Document

10.1016/j.dyepig.2011.02.002

Cite this

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title = "Hydrazones containing electron-accepting and electron-donating moieties",

abstract = "Hydrazones containing electron-accepting 1,8-naphthalimide species and electron-donating triphenylamino moieties were synthesized and characterized by nuclear magnetic resonance, infrared spectroscopy, and mass spectrometry. Thermal, optical, electrochemical and photophysical properties of the synthesized derivatives were investigated, their, optical and electrochemical band-gap energies and ionization potentials were established. The hydrazones exhibit initial mass loss temperatures in the range of 268-348 °C and can form glasses with glass transition temperatures in the range of 46-142 °C as established by differential scanning calorimetry. Room temperature time-of-flight hole mobilities in the solid solutions of the derivatives in the polymeric host bisphenol-Z polycarbonate (50\%) exceeded 10-5 cm 2/V s at high applied electric fields.",

keywords = "Charge mobility, Electron-accepting, Electron-donating, Glass-forming, Hydrazone, Ionization potential",

author = "D. Gudeika and R. Lygaitis and V. Mimaite and Grazulevicius, \{J. V.\} and V. Jankauskas and M. Lapkowski and P. Data",

year = "2011",

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doi = "10.1016/j.dyepig.2011.02.002",

language = "English",

volume = "91",

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journal = "Dyes and Pigments",

issn = "0143-7208",

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TY - JOUR

T1 - Hydrazones containing electron-accepting and electron-donating moieties

AU - Gudeika, D.

AU - Lygaitis, R.

AU - Mimaite, V.

AU - Grazulevicius, J. V.

AU - Jankauskas, V.

AU - Lapkowski, M.

AU - Data, P.

PY - 2011/10

Y1 - 2011/10

N2 - Hydrazones containing electron-accepting 1,8-naphthalimide species and electron-donating triphenylamino moieties were synthesized and characterized by nuclear magnetic resonance, infrared spectroscopy, and mass spectrometry. Thermal, optical, electrochemical and photophysical properties of the synthesized derivatives were investigated, their, optical and electrochemical band-gap energies and ionization potentials were established. The hydrazones exhibit initial mass loss temperatures in the range of 268-348 °C and can form glasses with glass transition temperatures in the range of 46-142 °C as established by differential scanning calorimetry. Room temperature time-of-flight hole mobilities in the solid solutions of the derivatives in the polymeric host bisphenol-Z polycarbonate (50%) exceeded 10-5 cm 2/V s at high applied electric fields.

AB - Hydrazones containing electron-accepting 1,8-naphthalimide species and electron-donating triphenylamino moieties were synthesized and characterized by nuclear magnetic resonance, infrared spectroscopy, and mass spectrometry. Thermal, optical, electrochemical and photophysical properties of the synthesized derivatives were investigated, their, optical and electrochemical band-gap energies and ionization potentials were established. The hydrazones exhibit initial mass loss temperatures in the range of 268-348 °C and can form glasses with glass transition temperatures in the range of 46-142 °C as established by differential scanning calorimetry. Room temperature time-of-flight hole mobilities in the solid solutions of the derivatives in the polymeric host bisphenol-Z polycarbonate (50%) exceeded 10-5 cm 2/V s at high applied electric fields.

KW - Charge mobility

KW - Electron-accepting

KW - Electron-donating

KW - Glass-forming

KW - Hydrazone

KW - Ionization potential

UR - https://www.scopus.com/pages/publications/79952780039

U2 - 10.1016/j.dyepig.2011.02.002

DO - 10.1016/j.dyepig.2011.02.002

M3 - Article

AN - SCOPUS:79952780039

SN - 0143-7208

VL - 91

SP - 13

EP - 19

JO - Dyes and Pigments

JF - Dyes and Pigments

IS - 1

ER -

Hydrazones containing electron-accepting and electron-donating moieties

Abstract

Keywords

ASJC Scopus subject areas

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