Copper (II) chloride / tetrabutylammonium bromide catalyzed oxidation of 2,6-diisopropylnaphthalene and 4,4′-diisopropylbiphenyl

Beata J. Orlińska; Jan M. Zawadiak

doi:10.2478/s11532-009-0134-8

Copper (II) chloride / tetrabutylammonium bromide catalyzed oxidation of 2,6-diisopropylnaphthalene and 4,4′-diisopropylbiphenyl

Beata J. Orlińska
, Jan M. Zawadiak

Department of Chemical Organic Technology and Petrochemistry (RCH/RCH5)

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The oxidation processes of 2,6-diisopropylnaphthalene and 4,4′-diisopropylbiphenyl with oxygen in the presence of a catalyst, composed of copper(II) chloride and tetrabutylammonium bromide, were investigated. It was found that, in essence, only one isopropyl group undergoes oxidation, and obtained mixtures contained mainly peroxide, alcohol, ketone and only small amounts of hydroperoxide.

Original language	English
Pages (from-to)	285-290
Number of pages	6
Journal	Central European Journal of Chemistry
Volume	8
Issue number	2
DOIs	https://doi.org/10.2478/s11532-009-0134-8
Publication status	Published - Apr 2010

Keywords

2,6-Diisopropylnaphthalene
4,4′-Diisopropylbiphenyl
Catalytic oxidation
Peroxides

ASJC Scopus subject areas

General Chemistry
Materials Chemistry

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10.2478/s11532-009-0134-8

Cite this

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title = "Copper (II) chloride / tetrabutylammonium bromide catalyzed oxidation of 2,6-diisopropylnaphthalene and 4,4′-diisopropylbiphenyl",

abstract = "The oxidation processes of 2,6-diisopropylnaphthalene and 4,4′-diisopropylbiphenyl with oxygen in the presence of a catalyst, composed of copper(II) chloride and tetrabutylammonium bromide, were investigated. It was found that, in essence, only one isopropyl group undergoes oxidation, and obtained mixtures contained mainly peroxide, alcohol, ketone and only small amounts of hydroperoxide.",

keywords = "2,6-Diisopropylnaphthalene, 4,4′-Diisopropylbiphenyl, Catalytic oxidation, Peroxides",

author = "Orli{\'n}ska, \{Beata J.\} and Zawadiak, \{Jan M.\}",

year = "2010",

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doi = "10.2478/s11532-009-0134-8",

language = "English",

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T1 - Copper (II) chloride / tetrabutylammonium bromide catalyzed oxidation of 2,6-diisopropylnaphthalene and 4,4′-diisopropylbiphenyl

AU - Orlińska, Beata J.

AU - Zawadiak, Jan M.

PY - 2010/4

Y1 - 2010/4

N2 - The oxidation processes of 2,6-diisopropylnaphthalene and 4,4′-diisopropylbiphenyl with oxygen in the presence of a catalyst, composed of copper(II) chloride and tetrabutylammonium bromide, were investigated. It was found that, in essence, only one isopropyl group undergoes oxidation, and obtained mixtures contained mainly peroxide, alcohol, ketone and only small amounts of hydroperoxide.

AB - The oxidation processes of 2,6-diisopropylnaphthalene and 4,4′-diisopropylbiphenyl with oxygen in the presence of a catalyst, composed of copper(II) chloride and tetrabutylammonium bromide, were investigated. It was found that, in essence, only one isopropyl group undergoes oxidation, and obtained mixtures contained mainly peroxide, alcohol, ketone and only small amounts of hydroperoxide.

KW - 2,6-Diisopropylnaphthalene

KW - 4,4′-Diisopropylbiphenyl

KW - Catalytic oxidation

KW - Peroxides

UR - https://www.scopus.com/pages/publications/77951862184

U2 - 10.2478/s11532-009-0134-8

DO - 10.2478/s11532-009-0134-8

M3 - Article

AN - SCOPUS:77951862184

SN - 1895-1066

VL - 8

SP - 285

EP - 290

JO - Central European Journal of Chemistry

JF - Central European Journal of Chemistry

IS - 2

ER -

Copper (II) chloride / tetrabutylammonium bromide catalyzed oxidation of 2,6-diisopropylnaphthalene and 4,4′-diisopropylbiphenyl

Abstract

Keywords

ASJC Scopus subject areas

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