Borenium ionic liquids as catalysts for Diels-Alder reaction: Tuneable Lewis superacids for catalytic applications

K. Matuszek; S. Coffie; A. Chrobok; M. Swadźba-Kwaśny

doi:10.1039/c7cy00106a

Borenium ionic liquids as catalysts for Diels-Alder reaction: Tuneable Lewis superacids for catalytic applications

K. Matuszek
, S. Coffie
, A. Chrobok
, M. Swadźba-Kwaśny

Department of Chemical Organic Technology and Petrochemistry (RCH/RCH5)

Silesian University of Technology
Queen's University Belfast

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Ionic liquids based on the tricoordinate borenium cation were used for the first time as Lewis acid catalysts for a model Diels-Alder reaction. The conversion of the dienophile was successfully correlated with the Gutmann acceptor number values of the ionic liquids. Borenium ionic liquids exceeded the performance of catalysts reported in the literature.

Original language	English
Pages (from-to)	1045-1049
Number of pages	5
Journal	Catalysis Science and Technology
Volume	7
Issue number	5
DOIs	https://doi.org/10.1039/c7cy00106a
Publication status	Published - 2017

ASJC Scopus subject areas

Catalysis

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10.1039/c7cy00106a

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title = "Borenium ionic liquids as catalysts for Diels-Alder reaction: Tuneable Lewis superacids for catalytic applications",

abstract = "Ionic liquids based on the tricoordinate borenium cation were used for the first time as Lewis acid catalysts for a model Diels-Alder reaction. The conversion of the dienophile was successfully correlated with the Gutmann acceptor number values of the ionic liquids. Borenium ionic liquids exceeded the performance of catalysts reported in the literature.",

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AU - Matuszek, K.

AU - Coffie, S.

AU - Chrobok, A.

AU - Swadźba-Kwaśny, M.

PY - 2017

Y1 - 2017

N2 - Ionic liquids based on the tricoordinate borenium cation were used for the first time as Lewis acid catalysts for a model Diels-Alder reaction. The conversion of the dienophile was successfully correlated with the Gutmann acceptor number values of the ionic liquids. Borenium ionic liquids exceeded the performance of catalysts reported in the literature.

AB - Ionic liquids based on the tricoordinate borenium cation were used for the first time as Lewis acid catalysts for a model Diels-Alder reaction. The conversion of the dienophile was successfully correlated with the Gutmann acceptor number values of the ionic liquids. Borenium ionic liquids exceeded the performance of catalysts reported in the literature.

UR - https://www.scopus.com/pages/publications/85026914573

U2 - 10.1039/c7cy00106a

DO - 10.1039/c7cy00106a

M3 - Article

AN - SCOPUS:85026914573

SN - 2044-4753

VL - 7

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JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

IS - 5

ER -

Borenium ionic liquids as catalysts for Diels-Alder reaction: Tuneable Lewis superacids for catalytic applications

Abstract

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