Badania właściwości elektrochemicznych i spektroelektrochemicznych (UV-Vis, EPR) pochodnych trimeru tiofenu podstawionych grupa̧ fenylowinylowa̧

MieczysŁaw ŁApkowski; MaŁgorzata Jadamiec; David L. Officer; Pawel Wagner; Agnieszka Stolarczyk; Keith C. Gordon; WiesŁaw W. SuŁkowski; Mariola Bartoszek

doi:10.14314/polimery.2009.209

Badania właściwości elektrochemicznych i spektroelektrochemicznych (UV-Vis, EPR) pochodnych trimeru tiofenu podstawionych grupa̧ fenylowinylowa̧

Translated title of the contribution: Investigations of electrochemical and spectroelectrochemical properties (UV-Vis, EPR) of thiophene trimer derivatives substituted with phenylvinyl groups

MieczysŁaw ŁApkowski
, MaŁgorzata Jadamiec
, David L. Officer
, Pawel Wagner
, Agnieszka Stolarczyk
, Keith C. Gordon
, WiesŁaw W. SuŁkowski
, Mariola Bartoszek

Polish Academy of Sciences
University of Wollongong
University of Otago
University of Silesia in Katowice

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The results of investigations concerning electrochemical properties of two thiophene trimers derivatives substituted with phenylvinyl groups {3′[(E)-2-phenylethenyl]-2,2′:5′,2″-thiophene (monomer A) and 4,4″-didecyloxy-3′[(E)-2-phenylethenyl]-2,2′:5′, 2″-thiophene (monomer B)} and the products of their oxidation were discussed. Electropolymerizations of A and B monomers were carried out with use of cyclic voltammetry and electrochemical measurements were coupled in-situ with spectroscopic methods (UV-Vis, EPR). It was found that A monomer oxidized to oligomers soluble in dichloromethane (Fig. 1-4 and 7) while monomer B showed ability to form stable conductive polymer layers showing low-energy forbidden band (1.6 eV) (Fig. 1, 5, 6 and 8, 9).

Translated title of the contribution	Investigations of electrochemical and spectroelectrochemical properties (UV-Vis, EPR) of thiophene trimer derivatives substituted with phenylvinyl groups
Original language	Polish
Pages (from-to)	209-215
Number of pages	7
Journal	Polimery/Polymers
Volume	54
Issue number	3
DOIs	https://doi.org/10.14314/polimery.2009.209
Publication status	Published - 2009

ASJC Scopus subject areas

General Chemical Engineering
Polymers and Plastics
Materials Chemistry

Access to Document

10.14314/polimery.2009.209

Cite this

@article{3a33dce3f458421d8b2f0afbb07bdf4b,

title = "Badania w{\l}a{\'s}ciwo{\'s}ci elektrochemicznych i spektroelektrochemicznych (UV-Vis, EPR) pochodnych trimeru tiofenu podstawionych grup{\c a} fenylowinylow{\c a}",

abstract = "The results of investigations concerning electrochemical properties of two thiophene trimers derivatives substituted with phenylvinyl groups \{3′[(E)-2-phenylethenyl]-2,2′:5′,2″-thiophene (monomer A) and 4,4″-didecyloxy-3′[(E)-2-phenylethenyl]-2,2′:5′, 2″-thiophene (monomer B)\} and the products of their oxidation were discussed. Electropolymerizations of A and B monomers were carried out with use of cyclic voltammetry and electrochemical measurements were coupled in-situ with spectroscopic methods (UV-Vis, EPR). It was found that A monomer oxidized to oligomers soluble in dichloromethane (Fig. 1-4 and 7) while monomer B showed ability to form stable conductive polymer layers showing low-energy forbidden band (1.6 eV) (Fig. 1, 5, 6 and 8, 9).",

keywords = "Conductive polymers, Electrochemical and spectroelectrochemical properties, Electropolymerization, Phenylvinyl group, Thiophene trimer",

author = "Mieczys{\L}aw {\L}Apkowski and Ma{\L}gorzata Jadamiec and Officer, \{David L.\} and Pawel Wagner and Agnieszka Stolarczyk and Gordon, \{Keith C.\} and Su{\L}kowski, \{Wies{\L}aw W.\} and Mariola Bartoszek",

year = "2009",

doi = "10.14314/polimery.2009.209",

language = "polski",

volume = "54",

pages = "209--215",

journal = "Polimery/Polymers",

issn = "0032-2725",

publisher = "Industrial Chemistry Research Institute",

number = "3",

}

TY - JOUR

T1 - Badania właściwości elektrochemicznych i spektroelektrochemicznych (UV-Vis, EPR) pochodnych trimeru tiofenu podstawionych grupa̧ fenylowinylowa̧

AU - ŁApkowski, MieczysŁaw

AU - Jadamiec, MaŁgorzata

AU - Officer, David L.

AU - Wagner, Pawel

AU - Stolarczyk, Agnieszka

AU - Gordon, Keith C.

AU - SuŁkowski, WiesŁaw W.

AU - Bartoszek, Mariola

PY - 2009

Y1 - 2009

N2 - The results of investigations concerning electrochemical properties of two thiophene trimers derivatives substituted with phenylvinyl groups {3′[(E)-2-phenylethenyl]-2,2′:5′,2″-thiophene (monomer A) and 4,4″-didecyloxy-3′[(E)-2-phenylethenyl]-2,2′:5′, 2″-thiophene (monomer B)} and the products of their oxidation were discussed. Electropolymerizations of A and B monomers were carried out with use of cyclic voltammetry and electrochemical measurements were coupled in-situ with spectroscopic methods (UV-Vis, EPR). It was found that A monomer oxidized to oligomers soluble in dichloromethane (Fig. 1-4 and 7) while monomer B showed ability to form stable conductive polymer layers showing low-energy forbidden band (1.6 eV) (Fig. 1, 5, 6 and 8, 9).

AB - The results of investigations concerning electrochemical properties of two thiophene trimers derivatives substituted with phenylvinyl groups {3′[(E)-2-phenylethenyl]-2,2′:5′,2″-thiophene (monomer A) and 4,4″-didecyloxy-3′[(E)-2-phenylethenyl]-2,2′:5′, 2″-thiophene (monomer B)} and the products of their oxidation were discussed. Electropolymerizations of A and B monomers were carried out with use of cyclic voltammetry and electrochemical measurements were coupled in-situ with spectroscopic methods (UV-Vis, EPR). It was found that A monomer oxidized to oligomers soluble in dichloromethane (Fig. 1-4 and 7) while monomer B showed ability to form stable conductive polymer layers showing low-energy forbidden band (1.6 eV) (Fig. 1, 5, 6 and 8, 9).

KW - Conductive polymers

KW - Electrochemical and spectroelectrochemical properties

KW - Electropolymerization

KW - Phenylvinyl group

KW - Thiophene trimer

UR - https://www.scopus.com/pages/publications/62149097135

U2 - 10.14314/polimery.2009.209

DO - 10.14314/polimery.2009.209

M3 - Artykuł

AN - SCOPUS:62149097135

SN - 0032-2725

VL - 54

SP - 209

EP - 215

JO - Polimery/Polymers

JF - Polimery/Polymers

IS - 3

ER -

Badania właściwości elektrochemicznych i spektroelektrochemicznych (UV-Vis, EPR) pochodnych trimeru tiofenu podstawionych grupa̧ fenylowinylowa̧

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this