Badania reakcji utleniającego rozszczepienia α-metylostyrenu tlenem wobec N-hydroksyftalimidu w alternatywnych rozpuszczalnikach

Gabriela Dobras; Dawid Lisicki; Dariusz Pyszny; Beata Orlińska

doi:10.15199/62.2019.4.19

Badania reakcji utleniającego rozszczepienia α-metylostyrenu tlenem wobec N-hydroksyftalimidu w alternatywnych rozpuszczalnikach

Translated title of the contribution: Studies on oxidative cleavage of α-methylstyrene with oxygen in the presence of N-hydroxyphthalimide in alternative solvents

Gabriela Dobras
, Dawid Lisicki
, Dariusz Pyszny
, Beata Orlińska

Department of Chemical Organic Technology and Petrochemistry (RCH/RCH5)

Silesian University of Technology

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

α-Methylstyrene was converted to AcPh and HCHO in the presence of N-hydroxyphthalimide, Co(II) acetylacetonate and azobis(isobutyronitrile) in ionic liqs. or supercrit. CO₂ as solvents (70 or 80°C). The conversion of α-methylstyrene was higher in ionic liq. than in crit. CO₂ but the selectivity to AcPh formation was higher in supercrit. CO₂ than in ionic liqs.

Translated title of the contribution	Studies on oxidative cleavage of α-methylstyrene with oxygen in the presence of N-hydroxyphthalimide in alternative solvents
Original language	Polish
Pages (from-to)	610-615
Number of pages	6
Journal	Przemysl Chemiczny
Volume	98
Issue number	4
DOIs	https://doi.org/10.15199/62.2019.4.19
Publication status	Published - Apr 2019

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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title = "Badania reakcji utleniaj{\c a}cego rozszczepienia α-metylostyrenu tlenem wobec N-hydroksyftalimidu w alternatywnych rozpuszczalnikach",

abstract = "α-Methylstyrene was converted to AcPh and HCHO in the presence of N-hydroxyphthalimide, Co(II) acetylacetonate and azobis(isobutyronitrile) in ionic liqs. or supercrit. CO2 as solvents (70 or 80°C). The conversion of α-methylstyrene was higher in ionic liq. than in crit. CO2 but the selectivity to AcPh formation was higher in supercrit. CO2 than in ionic liqs.",

author = "Gabriela Dobras and Dawid Lisicki and Dariusz Pyszny and Beata Orli{\'n}ska",

year = "2019",

month = apr,

doi = "10.15199/62.2019.4.19",

language = "polski",

volume = "98",

pages = "610--615",

journal = "Przemysl Chemiczny",

issn = "0033-2496",

publisher = "Wydawnictwo SIGMA - N O T Sp. z o.o.",

number = "4",

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T1 - Badania reakcji utleniającego rozszczepienia α-metylostyrenu tlenem wobec N-hydroksyftalimidu w alternatywnych rozpuszczalnikach

AU - Dobras, Gabriela

AU - Lisicki, Dawid

AU - Pyszny, Dariusz

AU - Orlińska, Beata

PY - 2019/4

Y1 - 2019/4

N2 - α-Methylstyrene was converted to AcPh and HCHO in the presence of N-hydroxyphthalimide, Co(II) acetylacetonate and azobis(isobutyronitrile) in ionic liqs. or supercrit. CO2 as solvents (70 or 80°C). The conversion of α-methylstyrene was higher in ionic liq. than in crit. CO2 but the selectivity to AcPh formation was higher in supercrit. CO2 than in ionic liqs.

AB - α-Methylstyrene was converted to AcPh and HCHO in the presence of N-hydroxyphthalimide, Co(II) acetylacetonate and azobis(isobutyronitrile) in ionic liqs. or supercrit. CO2 as solvents (70 or 80°C). The conversion of α-methylstyrene was higher in ionic liq. than in crit. CO2 but the selectivity to AcPh formation was higher in supercrit. CO2 than in ionic liqs.

UR - https://www.scopus.com/pages/publications/85069479760

U2 - 10.15199/62.2019.4.19

DO - 10.15199/62.2019.4.19

M3 - Artykuł

AN - SCOPUS:85069479760

SN - 0033-2496

VL - 98

SP - 610

EP - 615

JO - Przemysl Chemiczny

JF - Przemysl Chemiczny

IS - 4

ER -

Badania reakcji utleniającego rozszczepienia α-metylostyrenu tlenem wobec N-hydroksyftalimidu w alternatywnych rozpuszczalnikach

Abstract

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