Application of solid-liquid phase transfer catalysis system for peroxyester synthesis: A kinetic study of hydroperoxides acylation in the presence of solid sodium carbonate

Stefan Baj; Anna Chrobok; Izabela Gottwald

doi:10.1016/S0926-860X(01)00773-6

Application of solid-liquid phase transfer catalysis system for peroxyester synthesis: A kinetic study of hydroperoxides acylation in the presence of solid sodium carbonate

Stefan Baj
, Anna Chrobok
, Izabela Gottwald

Department of Chemical Organic Technology and Petrochemistry (RCH/RCH5)

Silesian University of Technology

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

In the research described below, we have developed a convenient and effective method of synthesis of organic peroxyesters to achieve 60-98% yields under extreme mild conditions. The study has been conducted on a model system using a reaction of acylation of 1-methyl-1-phenylethyl hydroperoxide (CHP) by means of butyryl chloride in the presence of solid Na₂CO₃ and being performed under conditions of phase transfer catalysis (PTC). The effect of the following parameters on the reaction was tested: temperature, Na₂CO₃ amount, catalyst structure and solvent polarity.

Original language	English
Pages (from-to)	89-95
Number of pages	7
Journal	Applied Catalysis A: General
Volume	224
Issue number	1-2
DOIs	https://doi.org/10.1016/S0926-860X(01)00773-6
Publication status	Published - 25 Jan 2002

Keywords

Acylation
Peroxyesters
Phase transfer catalysis
Sodium carbonate

ASJC Scopus subject areas

Catalysis
Process Chemistry and Technology

Access to Document

10.1016/S0926-860X(01)00773-6

Cite this

@article{c45db39d666c49f5946c5c3292bda09f,

title = "Application of solid-liquid phase transfer catalysis system for peroxyester synthesis: A kinetic study of hydroperoxides acylation in the presence of solid sodium carbonate",

abstract = "In the research described below, we have developed a convenient and effective method of synthesis of organic peroxyesters to achieve 60-98\% yields under extreme mild conditions. The study has been conducted on a model system using a reaction of acylation of 1-methyl-1-phenylethyl hydroperoxide (CHP) by means of butyryl chloride in the presence of solid Na2CO3 and being performed under conditions of phase transfer catalysis (PTC). The effect of the following parameters on the reaction was tested: temperature, Na2CO3 amount, catalyst structure and solvent polarity.",

keywords = "Acylation, Peroxyesters, Phase transfer catalysis, Sodium carbonate",

author = "Stefan Baj and Anna Chrobok and Izabela Gottwald",

year = "2002",

month = jan,

day = "25",

doi = "10.1016/S0926-860X(01)00773-6",

language = "English",

volume = "224",

pages = "89--95",

journal = "Applied Catalysis A: General",

issn = "0926-860X",

publisher = "Elsevier B.V.",

number = "1-2",

}

TY - JOUR

T1 - Application of solid-liquid phase transfer catalysis system for peroxyester synthesis

T2 - A kinetic study of hydroperoxides acylation in the presence of solid sodium carbonate

AU - Baj, Stefan

AU - Chrobok, Anna

AU - Gottwald, Izabela

PY - 2002/1/25

Y1 - 2002/1/25

N2 - In the research described below, we have developed a convenient and effective method of synthesis of organic peroxyesters to achieve 60-98% yields under extreme mild conditions. The study has been conducted on a model system using a reaction of acylation of 1-methyl-1-phenylethyl hydroperoxide (CHP) by means of butyryl chloride in the presence of solid Na2CO3 and being performed under conditions of phase transfer catalysis (PTC). The effect of the following parameters on the reaction was tested: temperature, Na2CO3 amount, catalyst structure and solvent polarity.

AB - In the research described below, we have developed a convenient and effective method of synthesis of organic peroxyesters to achieve 60-98% yields under extreme mild conditions. The study has been conducted on a model system using a reaction of acylation of 1-methyl-1-phenylethyl hydroperoxide (CHP) by means of butyryl chloride in the presence of solid Na2CO3 and being performed under conditions of phase transfer catalysis (PTC). The effect of the following parameters on the reaction was tested: temperature, Na2CO3 amount, catalyst structure and solvent polarity.

KW - Acylation

KW - Peroxyesters

KW - Phase transfer catalysis

KW - Sodium carbonate

UR - https://www.scopus.com/pages/publications/0037168859

U2 - 10.1016/S0926-860X(01)00773-6

DO - 10.1016/S0926-860X(01)00773-6

M3 - Article

AN - SCOPUS:0037168859

SN - 0926-860X

VL - 224

SP - 89

EP - 95

JO - Applied Catalysis A: General

JF - Applied Catalysis A: General

IS - 1-2

ER -

Application of solid-liquid phase transfer catalysis system for peroxyester synthesis: A kinetic study of hydroperoxides acylation in the presence of solid sodium carbonate

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this