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Aerobic oxidation of cumene catalysed by 4-Alkyloxycarbonyl-N- Hydroxyphthalimide

  • Silesian University of Technology

Research output: Contribution to journalArticlepeer-review

44 Citations (Scopus)

Abstract

4-Hexyloxycarbonyl-, 4-dodecyloxycarbonyl- and 4-hexadecyloxycarbonyl-N- hydroxyphthalimides were synthesised using trimellitic anhydride chloride as the starting material. The obtained lipophilic derivatives of N-hydroxyphthalimide were applied as catalysts of the cumene oxidation reaction with oxygen performed in polar acetonitrile, in non-polar tert-butylbenzene and in the absence of a solvent. The courses of reactions catalysed by N-hydroxyphthalimide and its derivatives were compared.

Original languageEnglish
Pages (from-to)1176-1182
Number of pages7
JournalCentral European Journal of Chemistry
Volume12
Issue number11
DOIs
Publication statusPublished - Oct 2014

Keywords

  • Cumene
  • N-Hydroxyphthalimide derivatives
  • Oxidation

ASJC Scopus subject areas

  • General Chemistry
  • Materials Chemistry

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